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食用油在煎炸过程中 3-单氯丙二醇酯和缩水甘油酯的生成。

The occurrence of 3-monochloropropane-1,2-diol esters and glycidyl esters in vegetable oils during frying.

机构信息

Product Development and Advisory Services Division, Malaysian Palm Oil Board, Kajang, Selangor, Malaysia.

出版信息

Crit Rev Food Sci Nutr. 2022;62(12):3403-3419. doi: 10.1080/10408398.2020.1865264. Epub 2021 Jan 5.

DOI:10.1080/10408398.2020.1865264
PMID:33397128
Abstract

3-monochloropropane-1,2-diol esters (3-MCPDE) and glycidyl esters (GE) are processed-developed contaminants presence in vegetable oils after undergo refining process under excessive heat. Refined oils are extensively used in various frying applications, nevertheless, the reservation against their quality and safety aspects are of major concern to consumers and food industry. Realizing the importance to address these issues, this article deliberates an overview of published studies on the manifestation of 3-MCPDE and GE when vegetable oils undergo for frying process. With the modest number of published frying research associated to 3-MCPDE and GE, we confined our review from the perspectives of frying conditions, product properties, antioxidants and additives, pre-frying treatments and frying oil management. Simplicity of the frying process is often denied by the complexity of reactions occurred between oil and food which led to the development of unwanted contaminants. The behavior of 3-MCPDE and GE is closely related to physico-chemical characteristics of oils during frying. As such, relationships between 3-MCPDE and/or GE with frying quality indices - i.e. acidity in term of free fatty acid or acid value); secondary oxidation in term of -anisidine value, total polar compounds and its fractions, and refractive index - were also discussed when oils were subjected under intermittent and continuous frying conditions.

摘要

3-单氯丙二醇酯(3-MCPDE)和缩水甘油酯(GE)是植物油在精炼过程中经历过度加热后产生的加工污染物。精炼油广泛用于各种油炸应用,但消费者和食品行业对其质量和安全方面的保留意见是主要关注点。意识到解决这些问题的重要性,本文综述了已发表的关于植物油在油炸过程中产生 3-MCPDE 和 GE 的研究。鉴于与 3-MCPDE 和 GE 相关的油炸研究数量有限,我们从油炸条件、产品特性、抗氧化剂和添加剂、预油炸处理和油炸油管理的角度限制了我们的综述。油炸过程的简单性往往被油和食物之间发生的反应的复杂性所否定,这些反应导致了不需要的污染物的产生。3-MCPDE 和 GE 的行为与油炸过程中油的物理化学特性密切相关。因此,当油在间歇和连续油炸条件下时,还讨论了 3-MCPDE 和/或 GE 与油炸质量指数(即游离脂肪酸或酸值表示的酸度);茴香胺值、总极性化合物及其分数和折射率表示的二次氧化)之间的关系。

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