钴催化芳基硼酸酯和乙烯基硼酸酯的原硼化反应
Cobalt-Catalyzed Protodeboronation of Aryl and Vinyl Boronates.
作者信息
Li Ninglin, Xiong Fuqiang, Gao Ke
机构信息
Hubei International Scientific and Technological Cooperation Base of Pesticide and Green Synthesis, Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079, P. R. China.
出版信息
J Org Chem. 2021 Jan 15;86(2):1972-1979. doi: 10.1021/acs.joc.0c02570. Epub 2021 Jan 5.
An efficient cobalt-based catalytic system for protodeboronation of various aryl and vinyl boronates is described. The reaction is capable of tolerating a wide range of functional groups. The reaction is also extended to deuterodeboronation with DO, which provides a potential protocol for the synthesis of regiospecifically deuterated arenes and olefins.
描述了一种用于各种芳基和乙烯基硼酸酯原硼氢化反应的高效钴基催化体系。该反应能够耐受多种官能团。该反应还扩展到用DO进行氘代硼氢化反应，这为区域特异性氘代芳烃和烯烃的合成提供了一种潜在的方法。
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