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铜配合物作为染料敏化太阳能电池中的替代氧化还原介体。

Copper Complexes as Alternative Redox Mediators in Dye-Sensitized Solar Cells.

机构信息

Department of Chemistry, University of Milan, UdR-INSTM, Via C. Golgi 19, I-20133 Milan, Italy.

出版信息

Molecules. 2021 Jan 2;26(1):194. doi: 10.3390/molecules26010194.

DOI:10.3390/molecules26010194
PMID:33401723
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7796243/
Abstract

Thirty years ago, dye-sensitized solar cells (DSSCs) emerged as a method for harnessing the sun's energy and converting it into electricity. Since then, a lot of work has been dedicated to improving their global photovoltaic efficiency and their eco-sustainability. Recently, various articles showed the great potential of copper complexes as a convenient and cheap alternative to the traditional ruthenium dyes. In addition, copper complexes demonstrate that they can act as redox mediators for DSSCs, thus being an answer to the problems related to the I/I redox couple. The aim of this review is to report on the most recent impact made by copper complexes as alternative redox mediators. The coverage, mainly from 2016 up to now, is not exhaustive, but allows us to understand the great role played by copper complexes in the design of eco-sustainable DSSCs.

摘要

三十年前，染料敏化太阳能电池 (DSSC) 作为一种利用太阳能并将其转化为电能的方法出现。从那时起，人们致力于提高其全球光伏效率和生态可持续性。最近，各种文章显示了铜配合物作为传统钌染料的便捷和廉价替代品的巨大潜力。此外，铜配合物表明它们可以作为 DSSC 的氧化还原介体，从而解决与 I/I 氧化还原对相关的问题。本综述的目的是报告铜配合物作为替代氧化还原介体的最新影响。报道主要集中在 2016 年至今，但足以让我们了解铜配合物在设计生态可持续 DSSC 中所起的重要作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1c52/7796243/f64c6ae7a901/molecules-26-00194-g007.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1c52/7796243/f64c6ae7a901/molecules-26-00194-g007.jpg

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