胺硼烷络合物引发的SFCl自由基对烯烃和炔烃的加成反应。

Amine-borane complex-initiated SFCl radical addition on alkenes and alkynes.

作者信息

Gilbert Audrey, Langowski Pauline, Delgado Marine, Chabaud Laurent, Pucheault Mathieu, Paquin Jean-François

机构信息

Départment de chimie, Université Laval, Québec, QC, G1V 0A6, Canada.

Institut des Sciences Moléculaires - Groupe ORGA - UMR 5255, Université de Bordeaux, 351 Cours de la libération, 33405 Talence, France.

出版信息

Beilstein J Org Chem. 2020 Dec 16;16:3069-3077. doi: 10.3762/bjoc.16.256. eCollection 2020.

The SFCl radical addition on unsaturated compounds was performed using an air-stable amine-borane complex as the radical initiator. This method showed to be complementary to the classic EtB-mediated SFCl addition on alkenes and alkynes. A total of seven alkene and three alkyne derivatives were tested in the reaction, with yields ranging from 3% to 85%.