A comprehensive review on the factors affecting thermochemical conversion efficiency of algal biomass to energy.

Algae are one of the most viable feedstock options that can be converted into different bioenergies viz., bioethanol, biobutanol, biodiesel, biomethane, biohydrogen, etc. owing to their renewable, sustainable and economic credibility features. Algal biomass to fuel biorefining process is generally classified into three categories as chemical, biochemical and thermochemical methods. The present article aims to provide a state-of-the-art review on the factors affecting the thermochemical conversion process of algal biomass to bioenergy. Further, reaction conditions of each techniques (torrefaction, pyrolysis, gasification and hydrothermal process) influence biochar, bio-oil and syngas yield were discussed. Reaction parameters or factors such as reactor temperature, residence time, pressure, biomass load/feedstock composition, catalyst addition and carrier gas flow affecting process efficiency in terms of product yield and quality were spotlighted and extensively discussed with copious literature. It also presents the novel insights on production of solid (char), liquid (bio-oil) and gaseous (syngas) biofuel through torrefaction, pyrolysis and gasification, respectively. It is found that the energy intensive drying was more efficient mode involved in thermochemical process for wet algal biomass. However other modes of thermochemical process were having unique feature on improving the product yield and quality. Among the various factors, reaction temperature and residence time were relatively more important factors which affected the process efficiency. The other factors signposted in this review will lay a roadmap to researchers to choose an optimal thermochemical conditions for high quality end product. Lastly, the perspectives and challenges in thermochemical conversion algae biomass to biofuels were also discussed.