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一种提高 α-FeO 光催化效率的策略。

A strategy to enhance the photocatalytic efficiency of α-FeO.

机构信息

Department of Physics, Alagappa University, Karaikudi, 630 003, Tamil Nadu, India.

Department of Physics, Alagappa University, Karaikudi, 630 003, Tamil Nadu, India.

出版信息

Chemosphere. 2021 May;270:129498. doi: 10.1016/j.chemosphere.2020.129498. Epub 2021 Jan 2.

Abstract

The photocatalytic dye degradation of pure α-FeO and different concentration of Co doped α-FeO is explored. Facile hydrothermal method were employed to prepare pristine, 2% and 4% Co-FeO nanoparticles. Further, synthesized product confirmation studies were employed from X-ray diffraction, UV-vis spectrometry, Fourier-transform infrared, Raman, scanning electron microscope and transmission electron microscope studies. The rhombohedral nanoparticles developed were enhanced photocatalytic action. Photocatalytic dye degradation studies were analyzed for prepared three samples and the photocatalytic efficacy of the obtained photocatalysts was compared experimentally. Methylene blue dye was degraded under UV-light irradiation with 364 nm. The results showed that 4% Co doped α-FeO sample exhibited better dye degradation with 92% efficiency. The 4% doping of cobalt ions enhanced the photocatalytic property of FeO and is a good candidate for methylene blue dye degradation above 90%. In addition, strategy for photocatalytic efficiency enhancement was proposed.

摘要

探索了纯 α-FeO 和不同浓度 Co 掺杂 α-FeO 的光催化染料降解。采用简便的水热法制备了原始、2%和 4% Co-FeO 纳米粒子。进一步,通过 X 射线衍射、紫外可见光谱、傅里叶变换红外、拉曼、扫描电子显微镜和透射电子显微镜研究对合成产物的确认研究。开发的菱面体纳米粒子增强了光催化作用。对制备的三种样品进行了光催化染料降解研究,并通过实验比较了获得的光催化剂的光催化效果。在 364nm 的紫外光照射下,亚甲基蓝染料被降解。结果表明,4% Co 掺杂的 α-FeO 样品表现出更好的染料降解效率,达到 92%。Co 离子的 4%掺杂增强了 FeO 的光催化性能,是一种在 90%以上降解亚甲基蓝染料的良好候选物。此外,还提出了提高光催化效率的策略。

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