Chang Haoxu, Wang Yayang, Qiao Panzhe, Sun Bo, Wang Zhengbang, Song Fei
Manchester Metropolitan Joint Institute, Hubei University, Wuhan 430062, China.
School of Materials Science and Engineering, Hubei University, Wuhan 430062, China.
Nanomaterials (Basel). 2024 Sep 4;14(17):1441. doi: 10.3390/nano14171441.
This study reports the synthesis of InVO/α-FeO heterojunction photocatalysts with different stoichiometric ratios via a two-step hydrothermal synthesis reaction. The prepared photocatalysts were characterized by XRD, SEM, TEM, XPS, and other methods. The prepared composites exhibited good photocatalysis of tetracycline hydrochloride. Among the InVO/α-FeO heterojunction photocatalysts with different ratios, the InVO/0.25α-FeO photocatalyst showed the highest degradation rate for 20 mg L tetracycline hydrochloride. After three photocatalytic runs, it still exhibited excellent stability and reusability. Meanwhile, this study also found that superoxide radical anion (-O), electron (e), hydroxyl radical (·OH), and photogenerated hole (h) are the basic active substances in the photocatalytic process.
本研究报道了通过两步水热合成反应制备不同化学计量比的InVO/α-FeO异质结光催化剂。采用XRD、SEM、TEM、XPS等方法对所制备的光催化剂进行了表征。所制备的复合材料对盐酸四环素表现出良好的光催化性能。在不同比例的InVO/α-FeO异质结光催化剂中,InVO/0.25α-FeO光催化剂对20 mg/L盐酸四环素的降解率最高。经过三次光催化循环后,它仍表现出优异的稳定性和可重复使用性。同时,本研究还发现超氧自由基阴离子(-O)、电子(e)、羟基自由基(·OH)和光生空穴(h)是光催化过程中的基本活性物质。