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电解强化生态浮床及其对模拟超富营养化水体中氮磷去除的影响因素

Electrolysis-enhanced ecological floating bed and its factors influencing nitrogen and phosphorus removal in simulated hyper-eutrophic water.

作者信息

Yan Cheng, Ma Tangming, Wang Mingxuan, Yang Shunqing, Yang Liuyan, Gao Yan

机构信息

State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing, 210023, People's Republic of China.

出版信息

Environ Sci Pollut Res Int. 2021 May;28(18):22832-22842. doi: 10.1007/s11356-020-12261-2. Epub 2021 Jan 11.

Abstract

To enhance ammonia nitrogen (NH-N) and phosphate (PO-P) removal in hyper-eutrophic water, electrolysis-enhanced ecological floating bed (EEEFB) was designed with a Mg-Al alloy anode, a Ir-Ta-Ti metal oxide-coated titanium anode, and an Fe anode with the same graphite cathode. The results showed that the Mg-Al alloy anode with graphite cathode had a better ability to enhance NH-N and PO-P removal. When the current density was 0.37 mA·cm, the electrolysis time was 24 h/d, and the net removal rates of NH-N and PO-P were 62% and 99.4%, respectively. In winter, the purification efficiencies of NH-N and PO-P were as high as 7388.4 mg·m and 4297.5 mg·m, respectively, by EEEFBs which were significantly higher than the traditional ecological floating bed (p < 0.05). Scanning electron microscopy (SEM) and X-ray spectrometry confirmed that the PO-P was deposited in the sediment of EEEFBs with Mg-Al alloy anode and Fe anode.

摘要

为提高超富营养化水体中氨氮(NH-N)和磷酸盐(PO-P)的去除效果,设计了一种电解强化生态浮床(EEEFB),其阳极分别为镁铝合金阳极、铱钽钛金属氧化物涂层钛阳极和铁阳极,阴极均为石墨。结果表明,镁铝合金阳极搭配石墨阴极在提高NH-N和PO-P去除能力方面表现更佳。当电流密度为0.37 mA·cm,电解时间为24 h/d时,NH-N和PO-P的净去除率分别为62%和99.4%。在冬季,EEEFB对NH-N和PO-P的净化效率分别高达7388.4 mg·m和4297.5 mg·m,显著高于传统生态浮床(p < 0.05)。扫描电子显微镜(SEM)和X射线光谱分析证实,PO-P沉积在采用镁铝合金阳极和铁阳极的EEEFB沉积物中。

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