State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing, 210046, People's Republic of China.
Yixing Environmental Research Institute of Nanjing University, Yixing, 214200, People's Republic of China.
Environ Sci Pollut Res Int. 2022 Nov;29(54):82574-82583. doi: 10.1007/s11356-022-21533-y. Epub 2022 Jun 25.
A novel method for remediating eutrophic lakes through electrolysis was made possible by one titanium (Ti) mesh, which serves as a cathode and two anodes of Ti mesh coated with ruthenium (IV) oxide and iridium (IV) oxide (RuO-IrO/Ti). Once the three-electrode components RuO-IrO/Ti and Ti are stabilized, they can carry out electrolytic reaction to control cyanobacteria blooms and assist with the remediation of eutrophic water. The order of influence on the theoretical energy consumption involved in removing algae is as follows: The electrode spacing was more effective than electrode voltage, which proved more effective than electrolysis time through the orthogonal test method. Thus, an electrode spacing of 60 mm, an electrode voltage of 30 V, and an electrolysis time of 12 h are the optimal electrolysis methods used to remove cyanobacterial blooms. The strong acidic environment produced by the anode increased the concentration of hydroxyl radical (•OH) and other strong oxidizing substances, which were the main roles that made cyanobacteria bloom inactivation. The electrolysis reaction was conducive to the transformation of organophosphorus in cyanobacterial blooms to dissolved inorganic phosphorus (DIP) in water. Some DIP was most deposited on the cathode after electro-depositing enhanced the removal of P in water with the 12-h prolonged electrolysis time. Meanwhile, it was beneficial to reduce the total nitrogen (TN) and ammonia nitrogen (NH-N) in the water. Thus, electrolysis proved to be an effective way to the inactivation of cyanobacteria blooms and simultaneously recover P as the concentration became higher.
一种通过电解修复富营养化湖泊的新方法成为可能,该方法使用一个钛(Ti)网作为阴极和两个涂有钌(IV)氧化物和铱(IV)氧化物的 Ti 网阳极(RuO-IrO/Ti)。一旦三电极组件 RuO-IrO/Ti 和 Ti 稳定,它们就可以进行电解反应来控制蓝藻水华并协助修复富营养化水。去除藻类的理论能耗的影响顺序如下:电极间距比电极电压更有效,而正交试验方法证明比电解时间更有效。因此,60mm 的电极间距、30V 的电极电压和 12h 的电解时间是去除蓝藻水华的最佳电解方法。阳极产生的强酸性环境增加了羟基自由基(•OH)和其他强氧化剂的浓度,这是使蓝藻水华失活的主要作用。电解反应有利于蓝藻水华中有机磷向水中溶解无机磷(DIP)的转化。随着 12 小时延长电解时间,电沉积增强了水中磷的去除,一些 DIP 最沉积在阴极上。同时,这有利于降低水中总氮(TN)和氨氮(NH-N)的浓度。因此,电解被证明是一种有效的蓝藻水华失活方法,同时随着浓度的升高而回收磷。