Band-Gap Tuning in All-Inorganic CsPbSnBr Perovskites.

We investigate all-inorganic perovskite CsPbSnBr thin films to determine the variations in the band gap and electronic structure associated with the Pb/Sn ratio. We observe that the band gap can be tuned between 1.86 eV ( = 0) and 2.37 eV ( = 1). Intriguingly, this change is nonlinear in , with a bowing parameter of 0.9 eV; furthermore, a slight band gap narrowing is found for low Pb content (minimum ∼ 0.3). The wide tunability of the band gap makes CsPbSnBr a promising material, e.g., for a wide-gap subcell in tandem applications or for color-tunable light-emitting diodes. Employing photoelectron spectroscopy, we show that the valence band varies with the Pb/Sn ratio, while the conduction band is barely affected.