Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory, Xianhu Hydrogen Valley, Foshan 528200, PR China; School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan 430070, PR China.
Department of Advanced Production Engineering, Engineering and Technology Institute Groningen, University of Groningen, Nijenborgh 4, 9747 AG Groningen, the Netherlands.
Carbohydr Polym. 2021 Mar 1;255:117469. doi: 10.1016/j.carbpol.2020.117469. Epub 2020 Dec 7.
Lithium-sulfur (Li-S) battery is considered to be a promising energy storage system due to its high energy density and low cost. However, the commercialization of Li-S battery is hindered by several problems such as the insulating nature of active materials, notorious "shuttle effect" and damage of lithium dendrites. Cellulose-based materials have attracted widespread attention in the development of Li-S battery on account of their environmentally friendly nature, unique network structure, and possibility for chemical functionalization. This review summarizes the application of cellulose-based materials in Li-S batteries mainly as either the separator, the carbon material for binder assisted modification of separator or as carbon hosts for sulfur cathode and discusses the challenges that utilization of the cellulose-based materials could potentially encountered in Li-S battery. Perspectives regarding the future development of cellulose-based materials for Li-S battery are also discussed.
锂硫(Li-S)电池因其高能量密度和低成本而被认为是一种很有前途的储能系统。然而,由于活性材料的绝缘性质、严重的“穿梭效应”和锂枝晶的损坏等问题,Li-S 电池的商业化受到阻碍。纤维素基材料因其环保性质、独特的网络结构和化学功能化的可能性,在 Li-S 电池的发展中引起了广泛的关注。本综述主要总结了纤维素基材料在 Li-S 电池中的应用,包括作为隔膜、用于隔膜粘结剂辅助修饰的碳材料或作为硫正极的碳载体,并讨论了在 Li-S 电池中使用纤维素基材料可能遇到的挑战。还讨论了纤维素基材料在 Li-S 电池未来发展方面的前景。