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混合淀粉/壳聚糖水凝胶:通过模拟退火算法模拟的弹性特性及其强烈减少黄色日落(INS 110)释放的能力。

Mixed starch/chitosan hydrogels: elastic properties as modelled through simulated annealing algorithm and their ability to strongly reduce yellow sunset (INS 110) release.

机构信息

Departamento de Tecnologia de Alimentos, Universidade Federal de Viçosa (UFV), Av. Peter Henry Rolfs, s/n, Campus Universitário, 36570-000, Viçosa, MG, Brazil.

Departamento de Tecnologia de Alimentos, Universidade Federal de Viçosa (UFV), Av. Peter Henry Rolfs, s/n, Campus Universitário, 36570-000, Viçosa, MG, Brazil.

出版信息

Carbohydr Polym. 2021 Mar 1;255:117526. doi: 10.1016/j.carbpol.2020.117526. Epub 2020 Dec 16.

DOI:10.1016/j.carbpol.2020.117526
PMID:33436258
Abstract

Biopolymers mixtures appear as a strategy to improve sensorial/technological characteristics of gel-like products. Thus, self-sustaining starch (S100/C0) hydrogels were prepared with a partial replacement of the gelling agent by 5.0 % (S95/C5), 7.5 % (S92.5/C7.5), or 10.0 % chitosan (S90/C10), and containing yellow sunset (INS 110). Major visual changes or significant differences on Lab* parameters were not observed for starch/chitosan hydrogels. Creep-recovery data was modeled using the simulated annealing algorithm, and relative recovery results showed an increase for S95/C5 (82.6 %), when compared to S100/C0 (72.9 %). After 312 h, chitosan strongly reduced the INS 110 release from hydrogels to an ethanolic solution (3.1∙10 and 4.1∙10 g/100 mL for S95/C5 and S100/C0, respectively) or to a sucrose solution (1.1∙10 and 6.5∙10 g/100 mL for S95/C5 and S100/C0, respectively). Such results highlighted that chitosan not only presented a techno-functionality on starch hydrogels by improving their elasticity but also by hindering the release of yellow sunset.

摘要

生物聚合物混合物作为一种策略,可以提高凝胶状产品的感官/技术特性。因此,用 5.0%(S95/C5)、7.5%(S92.5/C7.5)或 10.0%壳聚糖(S90/C10)部分替代胶凝剂制备了自支撑淀粉(S100/C0)水凝胶,并含有日落黄(INS110)。淀粉/壳聚糖水凝胶的 Lab*参数没有观察到明显的视觉变化或显著差异。使用模拟退火算法对蠕变恢复数据进行建模,相对恢复结果表明,与 S100/C0(72.9%)相比,S95/C5(82.6%)的恢复率有所增加。在 312 小时后,壳聚糖强烈减少了 INS110 从水凝胶到乙醇溶液(S95/C5 和 S100/C0 分别为 3.1×10 和 4.1×10 g/100 mL)或蔗糖溶液(S95/C5 和 S100/C0 分别为 1.1×10 和 6.5×10 g/100 mL)中的释放。这些结果表明,壳聚糖不仅通过提高淀粉水凝胶的弹性赋予其技术功能性,而且还阻碍了日落黄的释放。

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