钯/钯氧化还原和钯/钯非氧化还原催化循环的合并用于缺电子烯烃的烯丙基芳基化反应。
Merging Pd /Pd Redox and Pd /Pd Non-redox Catalytic Cycles for the Allylarylation of Electron-Deficient Alkenes.
机构信息
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
出版信息
Chemistry. 2021 Mar 12;27(15):5035-5040. doi: 10.1002/chem.202100075. Epub 2021 Feb 16.
PMID:33442926
Abstract
An allylarylation of electron-deficient alkenes with aryl boronates and allylic carbonates has been developed. This method allows access to a wide variety of carbon skeletons from readily available starting materials. Mechanistic studies indicate that this reaction is enabled by a cooperative catalysis based on merging Pd /Pd redox and Pd /Pd non-redox catalytic cycles.
摘要
一种烯丙基芳基硼酸酯和烯丙基碳酸酯与缺电子烯烃的 allylarylation 反应已被开发出来。该方法允许从易得的起始原料中获得多种碳骨架。机理研究表明，这种反应是通过基于合并 Pd / Pd 氧化还原和 Pd / Pd 非氧化还原催化循环的协同催化作用实现的。
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