钯/铜催化的缺电子烯烃的碳芳基化反应。
Carboallylation of electron-deficient alkenes by palladium/copper catalysis.
机构信息
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
出版信息
Chem Commun (Camb). 2018 Oct 9;54(81):11463-11466. doi: 10.1039/c8cc06023a.
PMID:30255872
Abstract
A method for the carboallylation of electron-deficient alkenes with tetraorganosilicon reagents and allylic carbonates based on Pd/Cu catalysis has been developed. This method affords a wide range of structurally diverse carbon skeletons from readily available starting materials, and tolerates various functional groups.
摘要
一种基于 Pd/Cu 催化的四有机硅试剂和烯丙基碳酸酯的缺电子烯烃的碳丙基化方法已经被开发出来。该方法可以从易得的起始原料得到广泛的结构多样的碳骨架，并且能够容忍各种官能团。
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