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Eu、Dy 共掺杂 SrMg(PO ) 荧光粉的自还原合成与发光性能。

Self-reduction synthesis and luminescence properties of Eu, Dy co-doped SrMg (PO ) phosphor.

机构信息

College of Materials Science and Engineering, Nanchang University, Nanchang, China.

College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, China.

出版信息

Luminescence. 2021 Jun;36(4):914-922. doi: 10.1002/bio.4015. Epub 2021 Feb 26.

Abstract

A series of SrMg (PO ) :Eu -Eu ,Dy phosphors was synthesized successfully using a high-temperature solid-state method in an air atmosphere. The structures were studied in detail using X-ray diffraction (XRD) and the luminescence properties of the samples. SrMg (PO ) :Eu -Eu samples can emit adjustable blue-violet light by controlling the proportion of dopant concentration of europium and dysprosium under 340 nm excitation. Dy exhibits typical blue and yellow emission under 350 nm excitation. The energy transferred from Eu to Dy in Dy and Eu co-doped system was determined by comparing the fluorescence spectra of single-doped system. In addition, the colour coordinates of the International Commission on lighting (CIE) indicated that SrMg (PO ) :Eu -Eu ,Dy could be considered as a potential blue-purple phosphor for white light-emitting diode applications.

摘要

采用高温固相法在空气气氛中成功合成了一系列 SrMg(PO4):Eu,Dy 荧光粉。通过 X 射线衍射(XRD)详细研究了样品的结构和发光性能。在 340nm 激发下,通过控制 Eu 和 Dy 掺杂浓度的比例,SrMg(PO4):Eu,Dy 样品可以发射可调谐的蓝紫光。在 350nm 激发下,Dy 呈现出典型的蓝、黄发射。通过比较单掺杂体系的荧光光谱,确定了 Dy 和 Eu 共掺杂体系中 Eu 向 Dy 的能量传递。此外,根据国际照明委员会(CIE)的色坐标,SrMg(PO4):Eu,Dy 可以被认为是一种潜在的用于白光发光二极管的蓝紫色荧光粉。

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