Department of Chemistry, University of California Santa Cruz, Santa Cruz, CA 95064, USA.
Chem Commun (Camb). 2021 Jan 28;57(9):1101-1104. doi: 10.1039/d0cc07405e. Epub 2021 Jan 18.
Both the instrumentation required for two photon excitation (TPE) and tissue damage possibility by high intensity laser lights could impede TPE-induced CO delivery in hospital settings. Herein we report two Mn(i)-based photoCORMs with a fac-{Mn(CO)} moiety that exhibit facile CO release upon simple exposure to light within the phototherapeutic region (no TPE required).
在医院环境中，实现双光子激发（TPE）所需的仪器设备以及高强度激光造成的组织损伤可能性，都可能会阻碍 TPE 诱导的 CO 传递。在此，我们报告了两种基于 Mn(i)的光控 CO 释放分子（photoCORMs），它们具有 fac-{Mn(CO)} 部分，在光疗区（无需 TPE）简单暴露于光线下即可轻易释放 CO。
