National Institute of Public Health, Šrobárova 49/48, Prague 10, 100 00, Czech Republic.
Environ Sci Process Impacts. 2021 Mar 4;23(2):311-322. doi: 10.1039/d0em00389a.
The modern, risk-based approach requires that only those pollutants which are likely to be present in a given water supply should be monitored in drinking water. From this perspective, defining an adequate approach to the monitoring of pesticides in areas with intensive agriculture is currently one of the greatest issues of regulation. This article shows the development and detailed results of pesticide monitoring in drinking water in the Czech Republic (CR). More than 4000 water supply zones serving around a 9.5 million population are routinely monitored, with nearly 250 thousand analyses of over 200 different pesticides and their metabolites being performed every year, with a non-compliance rate of ca. 0.3%. In 2017, pesticides accounted for most derogations in the CR, concerning a total of 64 water supply systems serving more than a 250 thousand population. A representative survey targeting 21 selected chemicals showed that 75% of water supply systems contained up to 11 pesticides per sample. The most commonly found were metabolites of the herbicides used to protect oilseed rape, maize, and sugar beet: acetochlor ESA, alachlor ESA, metazachlor OA, and chloridazon-desphenyl. The health risk assessment did not reveal any risks from these chemicals, even at the highest levels detected or in the most abundant mixtures, to the most vulnerable population (infants). Nevertheless, the increased presence of pesticides undermines the public's trust in drinking water safety.
现代的基于风险的方法要求仅监测那些在特定供水中可能存在的污染物。从这个角度来看,定义在农业集约化地区监测农药的适当方法是目前监管的最大问题之一。本文展示了捷克共和国(CR)饮用水中农药监测的发展和详细结果。超过 4000 个供水区为约 950 万人口提供服务,每年对近 25 万种不同农药及其代谢物进行约 25 万次分析,不遵守率约为 0.3%。2017 年,农药在 CR 中造成了大多数违规,涉及为超过 25 万人口服务的总共 64 个供水系统。一项针对 21 种选定化学物质的代表性调查显示,75%的供水系统每个样本中含有多达 11 种农药。最常见的是用于保护油菜、玉米和甜菜的除草剂的代谢物:乙草胺 ESA、甲草胺 ESA、异丙甲草胺 OA 和氯唑草酮-desphenyl。健康风险评估显示,即使在检测到的最高水平或最丰富的混合物中,这些化学物质对最脆弱的人群(婴儿)也没有任何风险。然而,农药的存在增加破坏了公众对饮用水安全的信任。