• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

通过直接颗粒挤出法制备的3D打印形状记忆聚合物。

3D Printed Shape Memory Polymers Produced via Direct Pellet Extrusion.

作者信息

Cersoli Trenton, Cresanto Alexis, Herberger Callan, MacDonald Eric, Cortes Pedro

机构信息

Civil/Environmental & Chemical Engineering, Rayen School of Engineering, Youngstown State University, Youngstown, OH 44555, USA.

Electrical Engineering, Rayen School of Engineering, Youngstown State University, Youngstown, OH 44555, USA.

出版信息

Micromachines (Basel). 2021 Jan 15;12(1):87. doi: 10.3390/mi12010087.

DOI:10.3390/mi12010087
PMID:33467774
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7829936/
Abstract

Shape memory polymers (SMPs) are materials capable of changing their structural configuration from a fixed shape to a temporary shape, and vice versa when subjected to a thermal stimulus. The present work has investigated the 3D printing process of a shape memory polymer (SMP)-based polyurethane using a material extrusion technology. Here, SMP pellets were fed into a printing unit, and actuating coupons were manufactured. In contrast to the conventional film-casting manufacturing processes of SMPs, the use of 3D printing allows the production of complex parts for smart electronics and morphing structures. In the present work, the memory performance of the actuating structure was investigated, and their fundamental recovery and mechanical properties were characterized. The preliminary results show that the assembled structures were able to recover their original conformation following a thermal input. The printed parts were also stamped with a QR code on the surface to include an unclonable pattern for addressing counterfeit features. The stamped coupons were subjected to a deformation-recovery shape process, and it was observed that the QR code was recognized after the parts returned to their original shape. The combination of shape memory effect with authentication features allows for a new dimension of counterfeit thwarting. The 3D-printed SMP parts in this work were also combined with shape memory alloys to create a smart actuator to act as a two-way switch to control data collection of a microcontroller.

摘要

形状记忆聚合物(SMPs)是一种材料,能够在受到热刺激时将其结构构型从固定形状转变为临时形状,反之亦然。目前的工作研究了使用材料挤出技术对基于形状记忆聚合物(SMP)的聚氨酯进行3D打印的过程。在这里,将SMP颗粒送入打印单元,并制造驱动试样。与传统的SMPs流延膜制造工艺相比,3D打印的使用允许生产用于智能电子和变形结构的复杂部件。在目前的工作中,研究了驱动结构的记忆性能,并对其基本恢复和力学性能进行了表征。初步结果表明,组装结构在热输入后能够恢复其原始构象。打印部件的表面还印有二维码,以包含用于解决假冒特征的不可克隆图案。对冲压试样进行变形-恢复形状过程,观察到部件恢复到原始形状后二维码仍能被识别。形状记忆效应与认证特征的结合为防伪提供了新的维度。这项工作中的3D打印SMP部件还与形状记忆合金相结合,创建了一个智能致动器,用作双向开关来控制微控制器的数据采集。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/789b/7829936/a0a566714b5f/micromachines-12-00087-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/789b/7829936/6112c4668567/micromachines-12-00087-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/789b/7829936/3eb3aa1f1ff5/micromachines-12-00087-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/789b/7829936/39e984b5f025/micromachines-12-00087-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/789b/7829936/db34040a4299/micromachines-12-00087-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/789b/7829936/a26d80cb3fb9/micromachines-12-00087-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/789b/7829936/701f294aa0ee/micromachines-12-00087-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/789b/7829936/7bfe706f6b4d/micromachines-12-00087-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/789b/7829936/9855b1d0b0d4/micromachines-12-00087-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/789b/7829936/a0a566714b5f/micromachines-12-00087-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/789b/7829936/6112c4668567/micromachines-12-00087-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/789b/7829936/3eb3aa1f1ff5/micromachines-12-00087-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/789b/7829936/39e984b5f025/micromachines-12-00087-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/789b/7829936/db34040a4299/micromachines-12-00087-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/789b/7829936/a26d80cb3fb9/micromachines-12-00087-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/789b/7829936/701f294aa0ee/micromachines-12-00087-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/789b/7829936/7bfe706f6b4d/micromachines-12-00087-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/789b/7829936/9855b1d0b0d4/micromachines-12-00087-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/789b/7829936/a0a566714b5f/micromachines-12-00087-g009.jpg

相似文献

1
3D Printed Shape Memory Polymers Produced via Direct Pellet Extrusion.通过直接颗粒挤出法制备的3D打印形状记忆聚合物。
Micromachines (Basel). 2021 Jan 15;12(1):87. doi: 10.3390/mi12010087.
2
Printing Parameters of Fused Filament Fabrication Affect Key Properties of Four-Dimensional Printed Shape-Memory Polymers.熔丝制造的打印参数影响四维打印形状记忆聚合物的关键性能。
3D Print Addit Manuf. 2023 Apr 1;10(2):279-288. doi: 10.1089/3dp.2021.0072. Epub 2023 Apr 12.
3
Shape-morphing composites with designed micro-architectures.具有设计微结构的形状变形复合材料。
Sci Rep. 2016 Jun 15;6:27933. doi: 10.1038/srep27933.
4
Color-Changeable Four-Dimensional Printing Enabled with Ultraviolet-Curable and Thermochromic Shape Memory Polymers.基于紫外光固化和热致变色形状记忆聚合物的颜色可变四维打印
ACS Appl Mater Interfaces. 2021 Apr 21;13(15):18120-18127. doi: 10.1021/acsami.1c02656. Epub 2021 Apr 8.
5
Mechanically Robust and UV-Curable Shape-Memory Polymers for Digital Light Processing Based 4D Printing.用于基于数字光处理的4D打印的机械坚固且可紫外光固化的形状记忆聚合物。
Adv Mater. 2021 Jul;33(27):e2101298. doi: 10.1002/adma.202101298. Epub 2021 May 17.
6
Additive Manufacturing of Information Carriers Based on Shape Memory Polyester Urethane.基于形状记忆聚酯聚氨酯的信息载体增材制造
Polymers (Basel). 2019 Jun 5;11(6):1005. doi: 10.3390/polym11061005.
7
Nucleation, Development and Healing of Micro-Cracks in Shape Memory Polyurethane Subjected to Subsequent Tension Cycles.形状记忆聚氨酯在后续拉伸循环作用下微裂纹的形核、扩展与愈合
Polymers (Basel). 2024 Jul 6;16(13):1930. doi: 10.3390/polym16131930.
8
Multi-shape active composites by 3D printing of digital shape memory polymers.通过数字形状记忆聚合物的3D打印制备的多形状活性复合材料。
Sci Rep. 2016 Apr 13;6:24224. doi: 10.1038/srep24224.
9
Multishape Programming of Shape Memory Polymer Assemblies Fabricated by Vat Photopolymerization-Based 3D Printing and Interfacial Welding.基于光固化3D打印和界面焊接制备的形状记忆聚合物组件的多形状编程
ACS Appl Mater Interfaces. 2023 Dec 13;15(49):57649-57655. doi: 10.1021/acsami.3c14140. Epub 2023 Nov 30.
10
Investigation of Shape Memory Polyurethane Properties in Cold Programming Process Towards Its Applications.面向应用的形状记忆聚氨酯在冷编程过程中的性能研究。
Polymers (Basel). 2024 Jan 12;16(2):219. doi: 10.3390/polym16020219.

引用本文的文献

1
Application of Reversible Four-Dimensional Printing of Shape Memory Alloys and Shape Memory Polymers in Structural Engineering: A State-of-the-Art Review.形状记忆合金和形状记忆聚合物的可逆四维打印在结构工程中的应用:最新综述
3D Print Addit Manuf. 2024 Jun 18;11(3):919-953. doi: 10.1089/3dp.2022.0376. eCollection 2024 Jun.
2
Metal and Polymer Based Composites Manufactured Using Additive Manufacturing-A Brief Review.基于增材制造的金属和聚合物基复合材料——简要综述
Polymers (Basel). 2023 Jun 2;15(11):2564. doi: 10.3390/polym15112564.
3
Development of Multiwalled Carbon Nanotubes/Halloysite Nanotubes Reinforced Thermal Responsive Shape Memory Polymer Nanocomposites for Enhanced Mechanical and Shape Recovery Characteristics in 4D Printing Applications.

本文引用的文献

1
Thermomechanical data of polyurethane shape memory polymer: Considering varying compositions.聚氨酯形状记忆聚合物的热机械数据:考虑不同组成。
Data Brief. 2020 Sep 9;32:106294. doi: 10.1016/j.dib.2020.106294. eCollection 2020 Oct.
2
A biodegradable functional water-responsive shape memory polymer for biomedical applications.一种用于生物医学应用的可生物降解的功能型水响应形状记忆聚合物。
J Mater Chem B. 2019 Jan 7;7(1):123-132. doi: 10.1039/c8tb02462f. Epub 2018 Dec 5.
3
Additive Manufacturing of Information Carriers Based on Shape Memory Polyester Urethane.
用于增强4D打印应用中机械性能和形状恢复特性的多壁碳纳米管/埃洛石纳米管增强热响应形状记忆聚合物纳米复合材料的研制
Polymers (Basel). 2023 Mar 9;15(6):1371. doi: 10.3390/polym15061371.
4
Material Extrusion of Helical Shape Memory Polymer Artificial Muscles for Human Space Exploration Apparatus.用于人类太空探索设备的螺旋形状记忆聚合物人工肌肉的材料挤出
Polymers (Basel). 2022 Dec 6;14(23):5325. doi: 10.3390/polym14235325.
5
Shape Memory Polymer-Based Endovascular Devices: Design Criteria and Future Perspective.基于形状记忆聚合物的血管内装置:设计标准与未来展望。
Polymers (Basel). 2022 Jun 21;14(13):2526. doi: 10.3390/polym14132526.
6
A Brief Review on Additive Manufacturing of Polymeric Composites and Nanocomposites.聚合物复合材料和纳米复合材料增材制造的简要综述
Micromachines (Basel). 2021 Jun 16;12(6):704. doi: 10.3390/mi12060704.
基于形状记忆聚酯聚氨酯的信息载体增材制造
Polymers (Basel). 2019 Jun 5;11(6):1005. doi: 10.3390/polym11061005.
4
Effect of Moisture on Shape Memory Polyurethane Polymers for Extrusion-Based Additive Manufacturing.水分对用于基于挤出的增材制造的形状记忆聚氨酯聚合物的影响。
Materials (Basel). 2019 Jan 12;12(2):244. doi: 10.3390/ma12020244.
5
Shape memory polymer network with thermally distinct elasticity and plasticity.具有热致不同弹性和塑性的形状记忆聚合物网络。
Sci Adv. 2016 Jan 8;2(1):e1501297. doi: 10.1126/sciadv.1501297. eCollection 2016 Jan.
6
3D Printing of Shape Memory Polymers for Flexible Electronic Devices.3D 打印形状记忆聚合物用于柔性电子设备。
Adv Mater. 2016 Jun;28(22):4449-54. doi: 10.1002/adma.201503132. Epub 2015 Sep 24.
7
pH-Responsive Shape Memory Poly(ethylene glycol)-Poly(ε-caprolactone)-based Polyurethane/Cellulose Nanocrystals Nanocomposite.基于pH响应形状记忆聚乙二醇-聚己内酯的聚氨酯/纤维素纳米晶体纳米复合材料
ACS Appl Mater Interfaces. 2015 Jun 17;7(23):12988-99. doi: 10.1021/acsami.5b02940. Epub 2015 Jun 2.
8
pH-induced shape-memory polymers.pH 响应形状记忆聚合物。
Macromol Rapid Commun. 2012 Jun 27;33(12):1055-60. doi: 10.1002/marc.201200153. Epub 2012 Apr 20.
9
Tunable polymer multi-shape memory effect.可调聚合物多形状记忆效应。
Nature. 2010 Mar 11;464(7286):267-70. doi: 10.1038/nature08863.