Zhang Jian, Yuan Wei, Xia Tian, Ao Chenghong, Zhao Jiangqi, Huang Bingxue, Wang Qunhao, Zhang Wei, Lu Canhui
State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute at Sichuan University, Chengdu 610065, China.
Advanced Polymer Materials Research Center of Sichuan University, Shishi 362700, China.
Nanomaterials (Basel). 2021 Jan 18;11(1):239. doi: 10.3390/nano11010239.
Carbon aerogels (CA) derived from bamboo cellulose fibers were coupled with TiO to form CA/TiO hybrids, which exhibited extraordinary performance on the photo-catalytic degradation of methylene blue (MB). The structure and morphology of CA/TiO were characterized by field emission scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction, and Raman spectrum. The CA displayed a highly porous and interconnected three-dimensional framework structure, while introducing the catalytic active sites of TiO onto the aerogel scaffold could remarkably enhance its photo-catalytic activity. The adsorption and photo-catalytic degradation of MB by the CA/TiO hybrid were investigated. The maximum adsorption capacity of CA/TiO for MB was 18.5 mg/g, which outperformed many similar materials reported in the literature. In addition, compared with other photo-catalysts, the present CA/TiO demonstrated superior photo-catalytic performance. Almost 85% of MB in 50 mL solution with a MB concentration of 10 mg/L could be effectively degraded by 15 mg CA/TiO in 300 min.
由竹纤维素纤维衍生而来的碳气凝胶(CA)与TiO耦合形成CA/TiO杂化物,其在亚甲基蓝(MB)的光催化降解方面表现出非凡性能。通过场发射扫描电子显微镜、傅里叶变换红外光谱、X射线光电子能谱、X射线衍射和拉曼光谱对CA/TiO的结构和形态进行了表征。CA呈现出高度多孔且相互连接的三维骨架结构,而将TiO的催化活性位点引入气凝胶支架可显著提高其光催化活性。研究了CA/TiO杂化物对MB的吸附和光催化降解。CA/TiO对MB的最大吸附容量为18.5 mg/g,优于文献报道的许多类似材料。此外,与其他光催化剂相比,目前的CA/TiO表现出优异的光催化性能。在300分钟内,15 mg CA/TiO可有效降解50 mL浓度为10 mg/L的MB溶液中近85%的MB。