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含席夫碱的新型环三磷腈衍生物的合成及其热性能和吸光度性能

Synthesis of new cyclotriphosphazene derivatives bearing Schiff bases and their thermal and absorbance properties.

作者信息

DoĞan Semih, TÜmay Süreyya Oğuz, Mutlu Balci Ceylan, YeŞİlot Serkan, BeŞlİ Serap

机构信息

Department of Chemistry, Faculty of Science, Gebze Technical University, Gebze, Kocaeli Turkey.

出版信息

Turk J Chem. 2020 Feb 11;44(1):31-47. doi: 10.3906/kim-1905-60. eCollection 2020.

DOI:10.3906/kim-1905-60
PMID:33488141
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7751826/
Abstract

In this study, a series of cyclotriphosphazene derivatives containing a Schiff base (3a-3d) were synthesized by the reactions of hexachlorocyclotriphosphazene (1) with bis-aryl Schiff bases ( - ) having different terminal groups (H, F, Cl, and Br). The products ( - ) were characterized by elemental and mass analyses, FT-IR, and H, C, and P NMR spectroscopies. Furthermore, the structure of compound was also determined by X-ray crystallography. The thermal behaviors and the spectral properties of the new cyclotriphosphazene compounds ( - ) were investigated and the results were compared in the series.

摘要

在本研究中，通过六氯环三磷腈（1）与具有不同端基（H、F、Cl和Br）的双芳基席夫碱（ - ）反应，合成了一系列含席夫碱的环三磷腈衍生物（3a - 3d）。产物（ - ）通过元素分析、质谱分析、傅里叶变换红外光谱（FT - IR）以及氢（¹H）、碳（¹³C）和磷（³¹P）核磁共振光谱进行表征。此外，化合物 的结构也通过X射线晶体学确定。研究了新型环三磷腈化合物（ - ）的热行为和光谱性质，并对该系列结果进行了比较。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/155d/7751826/7d12d951ddc3/turkjchem-44-31-fig011.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/155d/7751826/7d12d951ddc3/turkjchem-44-31-fig011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/155d/7751826/9c825e515a7e/turkjchem-44-31-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/155d/7751826/728a65b5d063/turkjchem-44-31-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/155d/7751826/9d6a0ac34b4d/turkjchem-44-31-fig001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/155d/7751826/a95579444455/turkjchem-44-31-fig002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/155d/7751826/ce2b6cb79532/turkjchem-44-31-fig003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/155d/7751826/834a544c87fd/turkjchem-44-31-fig004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/155d/7751826/907ebbf161f1/turkjchem-44-31-fig005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/155d/7751826/e35081bbec46/turkjchem-44-31-fig006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/155d/7751826/94aadd0325db/turkjchem-44-31-fig007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/155d/7751826/cd9ea79268ee/turkjchem-44-31-fig008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/155d/7751826/d852923bbd72/turkjchem-44-31-fig009.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/155d/7751826/7d12d951ddc3/turkjchem-44-31-fig011.jpg

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