School of Automotive and Traffic Engineering, Jiangsu University, Zhenjiang, 212203, China.
Environ Sci Pollut Res Int. 2021 Jun;28(21):26895-26905. doi: 10.1007/s11356-020-12277-8. Epub 2021 Jan 26.
Based on the rebound model of particle-wall collision, the influence of adhesion force on the deposition process of particles on the smoke cake wall was studied by using atomic force microscopy (AFM) and automatic specific surface area (BET) and pore size distribution analyzer. The interaction between the deposition process and the spatial structure of smoke cake was analyzed. The results show that with the increase of diesel engine speed, Young's modulus of particles decreases and the average particle size increases; the kinetic energy of particles impacting on the surface of smoke cake layer in diesel particle filter (DPF) increases; when the velocity of particles with the same particle size entering the wall increases, the maximum compression distance between particles and the surface of the smoke cake layer increases; and the adhesion force and adhesion energy increase. With the increase of diesel engine speed, the box counting dimension of smoke cake layer in DPF increases from 1.9478 to 1.996, the characteristic radius of pores decreases from 15.32 nm to 7.53 nm, the average pore diameter decreases, and the average pore volume increases. When the fractal dimension increases from 2.633 to 2.732, the deformation degree of particles increases, the smoke cake layer becomes more compact and dense, the internal structure of pores becomes more complex, the surface of pores is rougher, and particle adhesion requires overcoming larger adhesion barriers when particles adhere.
基于颗粒-壁碰撞的回弹模型,利用原子力显微镜(AFM)和自动比表面积(BET)及孔径分布分析仪研究了粘附力对颗粒在烟尘饼壁上沉积过程的影响。分析了沉积过程与烟尘饼空间结构的相互作用。结果表明,随着柴油机转速的增加,颗粒的杨氏模量降低,平均粒径增大;进入 DPF 中烟尘饼层的颗粒撞击表面的动能增加;当具有相同粒径的颗粒以相同的速度进入壁面时,颗粒与烟尘饼层表面之间的最大压缩距离增加;粘附力和粘附能增加。随着柴油机转速的增加,DPF 中烟尘饼层的盒计数维数从 1.9478 增加到 1.996,孔的特征半径从 15.32nm 减小到 7.53nm,平均孔径减小,平均孔体积增加。当分形维数从 2.633 增加到 2.732 时,颗粒的变形程度增加,烟尘饼层变得更加紧密和致密,孔的内部结构变得更加复杂,孔的表面更加粗糙,颗粒粘附时需要克服更大的粘附势垒。