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构建可磁回收的 ZnS-WO-CoFeO 纳米杂化富集光催化剂,用于可见光照射下 MB 染料的降解。

Construction of magnetically recoverable ZnS-WO-CoFeO nanohybrid enriched photocatalyst for the degradation of MB dye under visible light irradiation.

机构信息

Smart Materials Interface Laboratory, Department of Physics, Periyar University, Salem, 636 011, Tamilnadu, India.

Key Laboratory of Optoelectronic Devices and Systems of Guangdong Province, College of Optoelectronic Engineering, Shenzhen University, Shenzhen, Guangdong Province, 518060, PR China.

出版信息

Chemosphere. 2021 Jun;273:129687. doi: 10.1016/j.chemosphere.2021.129687. Epub 2021 Jan 19.

Abstract

Easily recyclable photocatalysts have received considerable attention for their practical application, in order to address the wastewater treatments. Here, we report efficient and magnetically recyclable ZnS-WO-CoFeO nanohybrid prepared through wet impregnation method. The photophysical and optical properties of as-prepared photocatalysts was investigated by different spectroscopic techniques. The photocatalytic activity of as synthesized samples were assessed by the photodegradation of methylene blue (MB) dye under visible light irradiation. Amongst, ZnS-WO-CoFeO nanohybrid exhibit higher photodegradation activity than the other bare and hybrid samples. The enhanced light absorption and lower emission intensity provide the improved photocatalytic activity of ZnS-WO-CoFeO nanohybrid. The ZnS-WO-CoFeO nanohybrid exhibit excellent photostability after four consecutive cycles. The ferromagnetic behavior of the hybrid sample using easily recover from the dye solution using an external bar magnet.

摘要

易于回收的光催化剂因其实际应用而受到广泛关注,以解决废水处理问题。在这里,我们报告了通过湿浸渍法制备的高效且可通过磁场回收的 ZnS-WO-CoFeO 纳米杂化材料。通过不同的光谱技术研究了所制备的光催化剂的光物理和光学性质。通过在可见光照射下光降解亚甲基蓝(MB)染料评估了合成样品的光催化活性。其中,ZnS-WO-CoFeO 纳米杂化材料比其他裸样和杂化样具有更高的光降解活性。增强的光吸收和较低的发射强度提供了 ZnS-WO-CoFeO 纳米杂化材料的改进的光催化活性。ZnS-WO-CoFeO 纳米杂化材料在连续四次循环后表现出优异的光稳定性。杂化样品具有铁磁性,可使用外部条形磁铁从染料溶液中轻易回收。

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