Lee Nahyeon, Kim Yong Tae, Lee Jechan
Department of Energy Systems Research, Ajou University, 206 Worldcup-ro, Suwon 16499, Korea.
C1 Gas & Carbon Convergent Research Center, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Daejeon 34114, Korea.
Polymers (Basel). 2021 Jan 24;13(3):364. doi: 10.3390/polym13030364.
Lignin directly derived from lignocellulosic biomass has been named a promising source of platform chemicals for the production of bio-based polymers. This review discusses potentially relevant routes to produce renewable aromatic aldehydes (e.g., syringaldehyde and vanillin) from lignin feedstocks (pre-isolated lignin or lignocellulose) that are used to synthesize a range of bio-based polymers. To do this, the processes to make aromatic aldehydes from lignin with their highest available yields are first presented. After that, the routes from such aldehydes to different polymers are explored. Challenges and perspectives of the production the lignin-derived renewable chemicals and polymers are also highlighted.
直接来源于木质纤维素生物质的木质素已被视为一种很有前景的平台化学品来源,可用于生产生物基聚合物。本综述讨论了从木质素原料(预分离木质素或木质纤维素)生产可再生芳香醛(如紫丁香醛和香草醛)的潜在相关途径,这些芳香醛可用于合成一系列生物基聚合物。为此,首先介绍了以最高产率从木质素制备芳香醛的工艺。之后,探索了从这些醛到不同聚合物的路线。还强调了生产木质素衍生的可再生化学品和聚合物所面临的挑战和前景。