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一种基于SnO-rGO杂化复合材料的高灵敏度室温CO气体传感器。

A Highly Sensitive Room Temperature CO Gas Sensor Based on SnO-rGO Hybrid Composite.

作者信息

Lee Zhi Yan, Hawari Huzein Fahmi Bin, Djaswadi Gunawan Witjaksono Bin, Kamarudin Kamarulzaman

机构信息

Department of Electrical and Electronics Engineering, Universiti Teknologi PETRONAS (UTP), Seri Iskandar 32610, Malaysia.

School of Mechatronics Engineering, Universiti Malaysia Perlis (UniMAP), Kangar 01000, Malaysia.

出版信息

Materials (Basel). 2021 Jan 22;14(3):522. doi: 10.3390/ma14030522.

Abstract

A tin oxide (SnO) and reduced graphene oxide (rGO) hybrid composite gas sensor for high-performance carbon dioxide (CO) gas detection at room temperature was studied. Since it can be used independently from a heater, it emerges as a promising candidate for reducing the complexity of device circuitry, packaging size, and fabrication cost; furthermore, it favors integration into portable devices with a low energy density battery. In this study, SnO-rGO was prepared via an in-situ chemical reduction route. Dedicated material characterization techniques including field emission scanning electron microscopy (FESEM), high-resolution transmission electron microscopy (HRTEM), energy dispersive X-ray (EDX) spectroscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS) were conducted. The gas sensor based on the synthesized hybrid composite was successfully tested over a wide range of carbon dioxide concentrations where it exhibited excellent response magnitudes, good linearity, and low detection limit. The synergistic effect can explain the obtained hybrid gas sensor's prominent sensing properties between SnO and rGO that provide excellent charge transport capability and an abundance of sensing sites.

摘要

研究了一种用于室温下高性能二氧化碳(CO)气体检测的氧化锡(SnO)与还原氧化石墨烯(rGO)混合复合气体传感器。由于它无需加热器即可独立使用,因此有望降低设备电路的复杂性、封装尺寸和制造成本;此外,它有利于集成到使用低能量密度电池的便携式设备中。在本研究中,通过原位化学还原路线制备了SnO-rGO。采用了包括场发射扫描电子显微镜(FESEM)、高分辨率透射电子显微镜(HRTEM)、能量色散X射线(EDX)光谱、拉曼光谱和X射线光电子能谱(XPS)在内的专用材料表征技术。基于合成的混合复合材料的气体传感器在广泛的二氧化碳浓度范围内成功进行了测试,表现出优异的响应幅度、良好的线性度和低检测限。协同效应可以解释所制备的混合气体传感器在SnO和rGO之间具有出色的传感特性,这些特性提供了优异的电荷传输能力和丰富的传感位点。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed6e/7865464/5da0ce3f9b44/materials-14-00522-g001.jpg

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