Corzo-Deluquez Enrique, Pineda-Muñoz Lina, Ruíz-Chamorro Adiela, Ocampo-López Carlos, Ramírez-Carmona Margarita, Rendón-Castrillón Leidy
Centro de Estudios y de Investigación en Biotecnología (CIBIOT), Facultad de Ingeniería Química, Universidad Pontificia Bolivariana, Circular 1ª No. 70-01, Medellín 050031, Colombia.
Entropy (Basel). 2021 Jan 25;23(2):142. doi: 10.3390/e23020142.
In this work, the production of biologically synthesized silica nanoparticles was proposed to prepare a nanosuspension as a thermal fluid in parabolic solar panels at the laboratory level. Silica nanoparticles were produced from construction sand in two stages. Biosynthesis broth was produced by aerated fermentation in a 1 L bioreactor for 9 days. Each supernatant was contacted with 18% construction sand in a 500 L reactor with mechanical agitation, at a temperature of 25 °C, and a contact time of 30 min. Subsequently, the separation process was carried out. For day 9, a pH value of 1.71 was obtained as well as acid concentrations of 15.78 g/L for citrus and 4.16 g/L for malic. The metal extraction efficiency of Si nanoparticles was 19%. The vibration peaks in the FTIR were characteristic of the presence of silica nanoparticles in wavenumbers 1020 cm and 1150 cm. Finally, a prototype solar radiation test bench for parabolic systems was built and provided with a radiation source that falls on a translucent pipe that transports the nanoparticles, which has a pump and a series of thermocouples. The heat capacity of the biotechnologically produced silica nanoparticle suspension was 0.72 ± 0.05 kJ/kgK, using material and energy balances in the flow circuit.
在这项工作中,提出了生物合成二氧化硅纳米颗粒的制备方法,以在实验室规模制备一种纳米悬浮液,作为抛物面太阳能板中的热流体。二氧化硅纳米颗粒分两个阶段由建筑砂制备。在1升生物反应器中通过曝气发酵9天来制备生物合成肉汤。将每种上清液在500升反应器中与18%的建筑砂在机械搅拌下接触,温度为25℃,接触时间为30分钟。随后进行分离过程。在第9天,获得的pH值为1.71,柑橘酸浓度为15.78克/升,苹果酸浓度为4.16克/升。硅纳米颗粒的金属提取效率为19%。傅里叶变换红外光谱(FTIR)中的振动峰在波数1020厘米和1150厘米处是二氧化硅纳米颗粒存在的特征。最后,搭建了一个用于抛物面系统的太阳能辐射测试台,配备了一个辐射源,该辐射源照射在输送纳米颗粒的半透明管道上,该管道有一个泵和一系列热电偶。利用流动回路中的物料和能量平衡,生物法生产的二氧化硅纳米颗粒悬浮液的热容为0.72±0.05千焦/千克·开尔文。