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6,6-二氟-6-二苯并[][1,2]氧杂硼杂环戊二烯阴离子与不同阳离子形成的两种盐。

Two salts of the 6,6-di-fluoro-6-dibenzo[,][1,2]oxaborinin-6-ide anion with different cations.

作者信息

Budanow Alexandra, Lerner Hans-Wolfram, Bolte Michael

机构信息

Institut für Anorganische und Analytische Chemie, Goethe-Universität Frankfurt, Max-von-Laue-Strasse 7, 60438 Frankfurt am Main, Germany.

出版信息

Acta Crystallogr E Crystallogr Commun. 2020 Nov 17;76(Pt 12):1837-1840. doi: 10.1107/S2056989020015066. eCollection 2020 Dec 1.

DOI:10.1107/S2056989020015066
PMID:33520264
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7784652/
Abstract

The crystal structures are reported of the 6,6-di-fluoro-6-dibenzo[,][1,2]oxaborinin-6-ide (or 9,9-di-fluoro-10-oxa-9-boraphenanthren-9-ide) anion with two different cations, namely, potassium 6,6-di-fluoro-6-dibenzo[,][1,2]oxaborinin-6-ide, K·CHBFO, (), featuring a polymeric structure, and bis-(tetra-phenyl-phospho-nium) bis-(6,6-di-fluoro-6-dibenzo[,][1,2]oxaborinin-6-ide) aceto-nitrile tris-olvate, 2CHP·2CHBFO·3CHCN, (), which is composed of discrete cations, anions and aceto-nitrile solvent mol-ecules linked by C-H⋯O, C-H⋯N and C-H⋯F hydrogen bonds. There are only minor differences in the geometrical parameters of the anions in these structures.

摘要

报道了6,6 - 二氟 - 6 - 二苯并[ ][1,2]氧杂硼杂环戊烯 - 6 - 负离子（或9,9 - 二氟 - 10 - 氧杂 - 9 - 硼杂菲 - 9 - 负离子）与两种不同阳离子所形成晶体结构，即6,6 - 二氟 - 6 - 二苯并[ ][1,2]氧杂硼杂环戊烯 - 6 - 钾盐K·CHBFO，（），具有聚合物结构，以及双（四苯基鏻）双（6,6 - 二氟 - 6 - 二苯并[ ][1,2]氧杂硼杂环戊烯 - 6 - 负离子）乙腈三溶剂合物2CHP·2CHBFO·3CHCN，（），它由离散的阳离子、阴离子和通过C - H⋯O、C - H⋯N和C - H⋯F氢键相连的乙腈溶剂分子组成。这些结构中阴离子的几何参数仅有微小差异。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f9f5/7784652/b452b237ff18/e-76-01837-fig7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f9f5/7784652/b52b5571b4a6/e-76-01837-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f9f5/7784652/b6b52b5f305b/e-76-01837-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f9f5/7784652/3ccc147958bc/e-76-01837-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f9f5/7784652/4fd76b16b8de/e-76-01837-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f9f5/7784652/3fbed5c02bc4/e-76-01837-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f9f5/7784652/2052a0b7331a/e-76-01837-fig6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f9f5/7784652/b452b237ff18/e-76-01837-fig7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f9f5/7784652/b52b5571b4a6/e-76-01837-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f9f5/7784652/b6b52b5f305b/e-76-01837-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f9f5/7784652/3ccc147958bc/e-76-01837-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f9f5/7784652/4fd76b16b8de/e-76-01837-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f9f5/7784652/3fbed5c02bc4/e-76-01837-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f9f5/7784652/2052a0b7331a/e-76-01837-fig6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f9f5/7784652/b452b237ff18/e-76-01837-fig7.jpg

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