The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials (State Key Laboratory Cultivation Base), College of Chemistry and Materials Science Anhui Normal University, Wuhu, Anhui 241002, P.R. China.
Dalton Trans. 2021 Feb 14;50(6):1995-2000. doi: 10.1039/d0dt04048g. Epub 2021 Feb 1.
Development of an efficient catalyst for degradation of organophosphorus toxicants is highly desirable. Herein, an MIL-101(Cr)LZn catalyst was fabricated by incorporating polypyridine zinc complexes into a MOF to achieve the spatial isolation of active sites. Compared with a terpyridine zinc complex without an MIL-101 support, this catalyst was highly active for detoxification of diethyl-4-nitrophenylphosphate.
开发高效的有机磷毒物降解催化剂是非常可取的。在此，通过将多吡啶锌配合物嵌入到 MOF 中，制备了 MIL-101(Cr)LZn 催化剂，以实现活性位点的空间隔离。与没有 MIL-101 载体的三吡啶锌配合物相比，该催化剂对二乙基-4-硝基苯基磷酸酯的解毒具有很高的活性。
