Müller Julian, Balázs Gábor, Scheer Manfred
Institut für Anorganische Chemie, Universität Regensburg, Regensburg 93040, Germany.
Chem Commun (Camb). 2021 Mar 2;57(18):2257-2260. doi: 10.1039/d0cc08328c.
The reactivity of [{Cp'''Fe(CO)2}2(μ,η1 : 1-P4)] (1) towards half-sandwich complexes of Ru(ii), Rh(iii), and Ir(iii) is studied. The coordination of these Lewis acids leads to a rearrangement of the P4 butterfly unit to form complexes with either an aromatic cyclo-P4R2 unit (R = Cp'''Fe(CO)2) or a catena-tetraphosphaene entity.
研究了[{Cp'''Fe(CO)₂}₂(μ,η¹ : ¹-P₄)] (1) 与Ru(ii)、Rh(iii)和Ir(iii)的半夹心配合物的反应活性。这些路易斯酸的配位导致P₄蝶形单元重排，形成具有芳族环-P₄R₂单元（R = Cp'''Fe(CO)₂）或链状四磷烯实体的配合物。
