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非热等离子体射流能量载体的光学特性及其在工业废水有效催化处理中的应用。

Optical characterization of non-thermal plasma jet energy carriers for effective catalytic processing of industrial wastewaters.

机构信息

Department of Physics, University of Agriculture, Faisalabad, 38040, Pakistan.

Department of Electrical Engineering, Namal Institute Mianwali, Mianwali, Pakistan.

出版信息

Sci Rep. 2021 Feb 3;11(1):2896. doi: 10.1038/s41598-021-82019-4.

DOI:10.1038/s41598-021-82019-4
PMID:33536469
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7859231/
Abstract

An argon plasma jet was sustained in open air and characterized for its chemical composition. The optically characterized plasma jet was used to treat industrial wastewater containing mixed textile dyes and heavy metals. Since plasma jet produces UV-radiations, the photocatalytic TiO was used to enhance plasma treatment efficiency especially for degradation of dyes. Mixed anatase and rutile phases of TiO (5.2-8.5 nm) were produced through surfactant assisted sol-gel approach. The emission spectrum confirmed the presence of excited argon, OH, excited nitrogen, excited oxygen, ozone and nitric oxide in the plasma jet. The spectral lines of excited Ar, NO, O, OH, N, [Formula: see text], O, [Formula: see text] and O species were observed at wavelength of 695-740 nm, 254.3 nm, 307.9 nm, 302-310 nm, 330-380 nm, 390-415 nm, 715.6 nm, 500-600 nm and 400-500 nm. These reactive species decompose the organic pollutants and separate the heavy metals from the water samples. The conductivity of plasma exposed water samples increased while pH and hardness decreased. The atomic absorption spectrophotometry analysis confirmed the presence of heavy metals in the samples, which were effectively removed through plasma treatment. Finally, the effect of plasma treatment on Staphylococcus aureus strains was more pronounced than Escherichia coli strains.

摘要

氩等离子体射流在空气中稳定存在,并对其化学成分进行了表征。经光学特性表征的等离子体射流用于处理含有混合纺织染料和重金属的工业废水。由于等离子体射流产生紫外线辐射,因此使用光催化剂 TiO 来提高等离子体处理效率,特别是用于染料的降解。通过表面活性剂辅助溶胶-凝胶法制备了混合锐钛矿和金红石相的 TiO(5.2-8.5nm)。发射光谱证实了等离子体射流中存在激发态氩、OH、激发态氮、激发态氧、臭氧和一氧化氮。观察到激发态 Ar、NO、O、OH、N、[Formula: see text]、O、[Formula: see text]和 O 物种的谱线位于 695-740nm、254.3nm、307.9nm、302-310nm、330-380nm、390-415nm、715.6nm、500-600nm 和 400-500nm。这些活性物质分解有机污染物并将重金属从水样中分离出来。等离子体暴露水样的电导率增加,而 pH 值和硬度降低。原子吸收分光光度法分析证实了样品中存在重金属,这些重金属通过等离子体处理有效去除。最后,等离子体处理对金黄色葡萄球菌菌株的影响比大肠杆菌菌株更为明显。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d87c/7859231/8825245fc9e9/41598_2021_82019_Fig14_HTML.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d87c/7859231/20456dd62486/41598_2021_82019_Fig12_HTML.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d87c/7859231/8825245fc9e9/41598_2021_82019_Fig14_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d87c/7859231/e9dbf795908b/41598_2021_82019_Fig1_HTML.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d87c/7859231/531cc29d9bc3/41598_2021_82019_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d87c/7859231/06decba04998/41598_2021_82019_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d87c/7859231/c2b951f76fd6/41598_2021_82019_Fig9_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d87c/7859231/9f6c2ae3a046/41598_2021_82019_Fig10_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d87c/7859231/9a0d0bc1ef4c/41598_2021_82019_Fig11_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d87c/7859231/20456dd62486/41598_2021_82019_Fig12_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d87c/7859231/c5ab18129bab/41598_2021_82019_Fig13_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d87c/7859231/8825245fc9e9/41598_2021_82019_Fig14_HTML.jpg

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