Yang Rui, Cheng Yuqing, Song Yujun, Belotelov Vladimir I, Sun Mengtao
School of Mathematics and Physics, Beijing Advanced Innovation Center for Materials Genome Engineering, University of Science and Technology Beijing, Beijing, 100083, China.
Russian Quantum Center, Moscow 143205, Russia, Lomonosov Moscow State University, Moscow, 11991, Russia.
Chem Rec. 2021 Apr;21(4):797-819. doi: 10.1002/tcr.202000171. Epub 2021 Feb 4.
In this review, we focus on the summary of catalytic reaction driven by surface plasmons and plexciton, where the plexciton is the interaction between plasmon and exciton. We first review the reduction and oxidation reactions driven by plasmons, and analyze the role of plasmons in the two reactions. We then summarize the recent research on the surface catalytic reactions driven by plasmon-exciton coupling and discuss the promotion effect of coupling interaction in oxidation reaction and reduction reaction. The coupling effect of plasmons and excitons can successfully improve the efficiency of catalytic reactions. Finally, this paper demonstrates the research progress in the electrooptical synergic plasmon-exciton co-driven surface catalytic reactions.
在本综述中，我们重点总结了由表面等离子体激元和极化激元驱动的催化反应，其中极化激元是等离子体激元和激子之间的相互作用。我们首先回顾了由等离子体激元驱动的氧化还原反应，并分析了等离子体激元在这两个反应中的作用。然后，我们总结了最近关于等离子体激元-激子耦合驱动的表面催化反应的研究，并讨论了耦合相互作用在氧化反应和还原反应中的促进作用。等离子体激元和激子的耦合效应能够成功提高催化反应的效率。最后，本文展示了电光协同的等离子体激元-激子共同驱动表面催化反应的研究进展。
