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基于铵的曝气控制提高了部分亚硝化-厌氧氨氧化反应器的氮去除效率并减少了氮氧化物排放。

Ammonium-based aeration control improves nitrogen removal efficiency and reduces NO emissions for partial nitritation-anammox reactors.

作者信息

Wan Xinyu, Baeten Janis E, Laureni Michele, Volcke Eveline I P

机构信息

BioCo Research Group, Department of Green Chemistry and Technology, Ghent University, Coupure Links 653, Ghent, 9000, Belgium.

BioCo Research Group, Department of Green Chemistry and Technology, Ghent University, Coupure Links 653, Ghent, 9000, Belgium; Environmental Biotechnology Group, Delft University of Technology, Mekelweg 5, Delft, CD, 2628, Netherlands.

出版信息

Chemosphere. 2021 Jul;274:129720. doi: 10.1016/j.chemosphere.2021.129720. Epub 2021 Jan 23.

Abstract

This study deals with the effect of aeration control strategies on the nitrogen removal efficiency and nitrous oxide (NO) emissions in a partial nitritation-anammox reactor with granular sludge. More specifically, dissolved oxygen (DO) control, constant airflow and effluent ammonium (NH) control strategies were compared through a simulation study. Particular attention was paid to the effect of flocs, which are deliberately or unavoidable present besides granules in this type of reactor. When applying DO control, DO setpoints had to be adjusted to the amount of flocs present in the reactor to maintain high nitrogen removal and reduce NO emissions, which is difficult to realize in practice because of variable floc fractions. Constant airflow rate control could maintain a good nitrogen removal efficiency independent of the floc fraction in the reactor, but failed in NO mitigation. Controlling aeration based on the effluent ammonium concentration results in both high nitrogen removal and relatively low NO emissions, also in the presence of flocs. Fluctuations in floc fractions caused significant upsets in nitrogen removal and NO emissions under DO control but had less effect at constant airflow and effluent ammonium control. Still, rapid and sharp drops in flocs led to a peak in NO emissions at constant airflow and effluent ammonium control. Overall, effluent ammonium control reached the highest average nitrogen removal and lowest NO emissions and consumed the lowest aeration energy under fluctuating floc concentrations.

摘要

本研究探讨了曝气控制策略对颗粒污泥亚硝化-厌氧氨氧化反应器中氮去除效率和一氧化二氮(N₂O)排放的影响。具体而言,通过模拟研究比较了溶解氧(DO)控制、恒定气流和出水铵(NH₄⁺)控制策略。特别关注了絮体的影响,在这类反应器中,除颗粒外,絮体是有意或不可避免存在的。应用DO控制时,DO设定值必须根据反应器中存在的絮体数量进行调整,以保持高氮去除率并减少N₂O排放,但由于絮体比例可变,这在实际中难以实现。恒定气流量控制可保持良好的氮去除效率,而与反应器中的絮体比例无关,但在减少N₂O排放方面效果不佳。基于出水铵浓度控制曝气,即使在存在絮体的情况下,也能实现高氮去除率和相对较低的N₂O排放。在DO控制下,絮体比例的波动会导致氮去除和N₂O排放出现显著波动,但在恒定气流和出水铵控制下影响较小。不过,絮体的快速急剧减少会导致在恒定气流和出水铵控制下N₂O排放出现峰值。总体而言,在絮体浓度波动的情况下,出水铵控制实现了最高的平均氮去除率、最低的N₂O排放,并消耗了最低的曝气能量。

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Pathways and Controls of NO Production in Nitritation-Anammox Biomass.亚硝化-厌氧氨氧化生物量中 NO 生成的途径和调控。
Environ Sci Technol. 2017 Aug 15;51(16):8981-8991. doi: 10.1021/acs.est.7b01225. Epub 2017 Jul 26.

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