Hioki Keiko
Corporate Research & Development Center, Daido Steel Co., Ltd., Nagoya, Japan.
Sci Technol Adv Mater. 2021 Jan 28;22(1):72-84. doi: 10.1080/14686996.2020.1868049.
Hot-deformed anisotropic Nd-Fe-B magnets may potentially attain high coercivity due to their fine and highly orientated crystal grain microstructure as a result of the unique production process that creates these magnets. However, despite their fine grain size of 100-500 nm, coercivity was only around 25% of the full potential of the anisotropy field. This grain size was close to the critical diameter of the single domain grain size of the Nd-Fe-B magnet. This study investigated the effects of chemical composition and deformation conditions on the magnetic properties of Nd-Fe-B magnets, observing their microstructure to obtain guidance on the ideal microstructure. We also improved the hot-deformation technique in parallel to optimize microstructure by controlling the compositions and hot-deformation conditions based on the results of basic studies. Lastly, we fabricated heavy rare-earth-free magnets with a coercivity exceeding 1600 kA/m (20 kOe), which is 20% higher than that of conventional magnets.
热变形各向异性钕铁硼磁体由于其独特的生产工艺所形成的精细且高度取向的晶粒微观结构,可能具有高矫顽力。然而,尽管其晶粒尺寸为100 - 500纳米,矫顽力仅约为各向异性场全势的25%。此晶粒尺寸接近钕铁硼磁体单畴晶粒尺寸的临界直径。本研究调查了化学成分和变形条件对钕铁硼磁体磁性能的影响,观察其微观结构以获取理想微观结构的指导。我们还并行改进了热变形技术,根据基础研究结果通过控制成分和热变形条件来优化微观结构。最后,我们制造出了矫顽力超过1600 kA/m(20 kOe)的无重稀土磁体,比传统磁体高20%。