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通过滴涂法在碳毡阳极上修饰双金属氧化物 MnFeO:一种有效提高微生物燃料电池发电性能的方法。

Bimetallic oxide MnFeO modified carbon felt anode by drip coating: an effective approach enhancing power generation performance of microbial fuel cell.

机构信息

National Key Laboratory of High-Efficiency Utilization of Coal and Green Chemical Engineering, Ningxia University, Yinchuan, 750021, People's Republic of China.

出版信息

Bioprocess Biosyst Eng. 2021 Jun;44(6):1119-1130. doi: 10.1007/s00449-021-02511-z. Epub 2021 Feb 8.

Abstract

The anode electrode of microbial fuel cell (MFC) is the key component to determine its power generation performance because it is the habitat and electron transfer center of the electricity-producing microorganisms. Carbon-based anodes have been confirmed to improve MFC performance. Its large surface area, excellent conductivity and low cost make it very suitable for electrode materials used in MFC. However, the low biocompatibility and instability of common carbon-based materials restrict their practical application in MFC. In this work, a bimetal oxide MnFeO was prepared and used to modify carbon felt anode by a simple drop coating method. The influence of the amount of MnFeO material on the performance of MFC was systematically studied. The results showed that the power density of the carbon felt anode with a MnFeO modified amount of 1 mg/cm increased by 66.9% compared with the unmodified anode. Meanwhile, the MFC cycle using MnFeO modified anode was more stable. After 6 months of long-term operation, the power density reached 3836 mW/m. The anode modified by MnFeO has capacitance characteristics, good biocompatibility and fast electron transmission rate, which significantly improves the power generation performance of MFC. In addition, the use of a simple drop coating method to prepare electrodes can reduce the difficulty of electrode fabrication and the cost of MFC, laying a certain foundation for the industrialization of MFC.

摘要

微生物燃料电池(MFC)的阳极电极是决定其发电性能的关键组件,因为它是产电微生物的栖息地和电子转移中心。碳基阳极已被证实可以提高 MFC 的性能。其较大的表面积、优异的导电性和低成本使其非常适合用作 MFC 中的电极材料。然而,常见碳基材料的低生物相容性和不稳定性限制了它们在 MFC 中的实际应用。在这项工作中,制备了一种双金属氧化物 MnFeO,并通过简单的滴涂法来修饰碳毡阳极。系统研究了 MnFeO 材料添加量对 MFC 性能的影响。结果表明,与未修饰的阳极相比,MnFeO 修饰量为 1 mg/cm 的碳毡阳极的功率密度提高了 66.9%。同时,使用 MnFeO 修饰阳极的 MFC 循环更加稳定。经过 6 个月的长期运行,功率密度达到 3836 mW/m。经过 MnFeO 修饰的阳极具有电容特性、良好的生物相容性和快速的电子传递速率,显著提高了 MFC 的发电性能。此外,使用简单的滴涂法制备电极可以降低电极制造的难度和 MFC 的成本,为 MFC 的产业化奠定了一定的基础。

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