源自扭曲多环芳烃的π-互穿三维共价有机框架
π-Interpenetrated 3D Covalent Organic Frameworks from Distorted Polycyclic Aromatic Hydrocarbons.
作者信息
Martínez-Abadía Marta, Strutyński Karol, Lerma-Berlanga Belén, Stoppiello Craig T, Khlobystov Andrei N, Martí-Gastaldo Carlos, Saeki Akinori, Melle-Franco Manuel, Mateo-Alonso Aurelio
机构信息
POLYMAT, University of the Basque Country UPV/EHU, Avenida de Tolosa 72, 20018, Donostia-San Sebastian, Spain.
CICECO-Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193, Aveiro, Portugal.
出版信息
Angew Chem Int Ed Engl. 2021 Apr 26;60(18):9941-9946. doi: 10.1002/anie.202100434. Epub 2021 Mar 18.
Three-dimensional covalent organic frameworks (3D COFs) with a pcu topology have been obtained from distorted polycyclic aromatic hydrocarbons acting as triangular antiprismatic (D ) nodes. Such 3D COFs are six-fold interpenetrated as the result of interframework π-stacking, which enable charge transport properties that are not expected for 3D COFs.
具有pcu拓扑结构的三维共价有机框架（3D COFs）是由扭曲的多环芳烃作为三角反棱柱形（D）节点制得的。由于框架间的π堆积，此类3D COFs具有六重互穿结构，这使其具备了三维共价有机框架所不具备的电荷传输特性。
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