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具有介电/金属/介电顶电极的半透明有机光伏电池：金属对其性能的影响。

Semi-Transparent Organic Photovoltaic Cells with Dielectric/Metal/Dielectric Top Electrode: Influence of the Metal on Their Performances.

作者信息

Cattin Linda, Louarn Guy, Morsli Mustapha, Bernède Jean Christian

机构信息

Institut des Matériaux Jean Rouxel (IMN), Université de Nantes, CNRS, UMR 6502, 2 rue de la Houssinière, BP 92208, F-44322 Nantes, France.

Faculté des Sciences et des Techniques, Université de Nantes, 2 rue de la Houssinière, BP 92208, F-44000 Nantes, France.

出版信息

Nanomaterials (Basel). 2021 Feb 4;11(2):393. doi: 10.3390/nano11020393.

DOI:10.3390/nano11020393
PMID:33557016
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7913718/
Abstract

In order to grow semi-transparent organic photovoltaic cells (OPVs), multilayer dielectric/metal/dielectric (D/M/D) structures are used as a transparent top electrode in inverted OPVs. Two different electrodes are probed, MoO/Ag/MoO and MoO/Ag/Cu:Ag/ZnS. Both of them exhibit high transmission in visible and small sheet resistance. Semi-transparent inverted OPVs using these electrodes as the top anode are probed. The active organic layers consist in the SubPc/C couple. The dependence of the OPV performances on the top electrode was investigated. The results show that far better results are achieved when the top anode MoO/Ag/MoO is used. The OPV efficiency obtained was only 20% smaller in comparison with the opaque OPV, but with a transparency of nearly 50% in a broad range of the visible light (400-600 nm). In the case of MoO/Ag/Cu:Ag/ZnS top anode, the small efficiency obtained is due to the presence of some Cu diffusion in the MoO layer, which degrades the contact anode/organic material.

摘要

为了生长半透明有机光伏电池（OPV），多层介质/金属/介质（D/M/D）结构被用作倒置OPV中的透明顶电极。研究了两种不同的电极，即MoO/Ag/MoO和MoO/Ag/Cu:Ag/ZnS。它们在可见光范围内均具有高透射率且薄层电阻较小。对使用这些电极作为顶阳极的半透明倒置OPV进行了研究。活性有机层由SubPc/C组成。研究了OPV性能对顶电极的依赖性。结果表明，当使用顶阳极MoO/Ag/MoO时可获得更好的结果。与不透明OPV相比，所获得的OPV效率仅低20%，但在很宽的可见光范围（400 - 600 nm）内透明度接近50%。在使用MoO/Ag/Cu:Ag/ZnS作为顶阳极的情况下，所获得的效率较低是由于MoO层中存在一些铜扩散，这会降低阳极/有机材料之间的接触。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5b1c/7913718/1da52cc744e7/nanomaterials-11-00393-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5b1c/7913718/a29b8844f00d/nanomaterials-11-00393-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5b1c/7913718/8f4af6b7340e/nanomaterials-11-00393-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5b1c/7913718/c48ef9e65e0b/nanomaterials-11-00393-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5b1c/7913718/0da80ca28fe4/nanomaterials-11-00393-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5b1c/7913718/2f5d0b77f542/nanomaterials-11-00393-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5b1c/7913718/1da52cc744e7/nanomaterials-11-00393-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5b1c/7913718/a29b8844f00d/nanomaterials-11-00393-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5b1c/7913718/8f4af6b7340e/nanomaterials-11-00393-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5b1c/7913718/c48ef9e65e0b/nanomaterials-11-00393-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5b1c/7913718/0da80ca28fe4/nanomaterials-11-00393-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5b1c/7913718/2f5d0b77f542/nanomaterials-11-00393-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5b1c/7913718/1da52cc744e7/nanomaterials-11-00393-g006.jpg

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