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五种蜡烛在稳定燃烧条件下的超细颗粒排放。

Emissions of ultrafine particles from five types of candles during steady burn conditions.

作者信息

Rasmussen Berit B, Wang Kai, Karstoft Johan G, Skov Søren N, Køcks Morten, Andersen Christina, Wierzbicka Aneta, Pagels Joakim, Pedersen Peter B, Glasius Marianne, Bilde Merete

机构信息

Department of Chemistry, Aarhus University, Aarhus C, Denmark.

College of Resources and Environmental Sciences, National Academy of Agriculture Green Development, China Agricultural University, Beijing, China.

出版信息

Indoor Air. 2021 Jul;31(4):1084-1094. doi: 10.1111/ina.12800. Epub 2021 Feb 10.

Abstract

Emissions from candles are of concern for indoor air quality. In this work, five different types of pillar candles were burned under steady burn conditions in a new laboratory scale system for repeatable and controlled comparison of candle emissions (temperature 25°C, relative humidity ~13%, O >18%, air exchange rate 1.9 h ). Burn rate, particle number concentrations, mass concentrations, and mode diameters varied between candle types. Based on the results, the burning period was divided in two phases: initial (0-1 h) and stable (1-6 h). Burn rates were in the range 4.4-7.3 and 4.7-7.1 g/h during initial and stable phase, respectively. Relative particle number emissions, mode diameters, and mass concentrations were higher during the initial phase compared to the stable phase for a majority of the candles. We hypothesize that this is due to elevated emissions of wick additives upon ignition of the candle together with a slightly higher burn rate in the initial phase. Experiments at higher relative humidity (40%) gave similar results with a tendency toward larger particle sizes at the higher relative humidity. Chemical composition with respect to inorganic salts was similar in the emitted particles (dry conditions) compared to the candlewicks, but with variations between different candles.

摘要

蜡烛排放物关乎室内空气质量。在本研究中,五种不同类型的柱状蜡烛在一个新的实验室规模系统中于稳定燃烧条件下燃烧,以便对蜡烛排放物进行可重复且可控的比较(温度约25°C,相对湿度约13%,氧气含量>18%,空气交换率1.9次/小时)。不同蜡烛类型的燃烧速率、颗粒数浓度、质量浓度和模态直径各不相同。基于这些结果,燃烧期分为两个阶段:初始阶段(0 - 1小时)和稳定阶段(1 - 6小时)。初始阶段和稳定阶段的燃烧速率分别在4.4 - 7.3克/小时和4.7 - 7.1克/小时范围内。对于大多数蜡烛而言,初始阶段的相对颗粒数排放、模态直径和质量浓度高于稳定阶段。我们推测这是由于蜡烛点燃时灯芯添加剂的排放量增加,以及初始阶段的燃烧速率略高所致。在较高相对湿度(约40%)下进行的实验得到了类似结果,且在较高相对湿度下颗粒尺寸有变大的趋势。与烛芯相比,排放颗粒(干燥条件下)中无机盐的化学成分相似,但不同蜡烛之间存在差异。

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