Guo Zhiguang, Sun Chao, Wang Juan, Cai Zaisheng, Ge Fengyan
College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai201620, China.
Technology Innovation Center of Hebei for Fiber Material, Shijiazhuang University, Shijiazhuang, Hebei050035, China.
ACS Appl Mater Interfaces. 2021 Feb 24;13(7):8851-8862. doi: 10.1021/acsami.0c23123. Epub 2021 Feb 10.
Multifunctional wearable heaters have attracted much attention owing to their efficient application in personal thermal management. Inspired by the polar bear's thermal management, a laminated fabric with enhanced photothermal conversion, mid-infrared reflection, thermal insulation, and electrical heating performance was developed in this work, which was made of CNT/cellulose aerogel layers, cotton fabrics, and copper nanowire (CuNW)-based conductive network (CNN) layers. The CNN layer made up of highly conductive CuNWs not only exhibits better conductivity to realize the Joule heating effect but also possesses a human mid-infrared reflection property. Moreover, the other side of the cotton fabric was laminated with CNT/cellulose aerogel, which enables the fabric to have a good photothermal conversion ability and thermal insulation performance. The temperature of the laminated fabric could reach to 70 °C within 80 s under 1.8 V; it requires more than 500 s to return to room temperature (28.7 °C). When the light intensity was adjusted to 1000 W/m, the temperature of the laminated fabric was about 74.0 °C after lighting for 280 s. Our work provides a new approach to improving the performance and energy-saving of personal thermal management fabrics.
多功能可穿戴加热器因其在个人热管理中的高效应用而备受关注。受北极熊热管理的启发,本研究开发了一种具有增强光热转换、中红外反射、隔热和电加热性能的层压织物,它由碳纳米管/纤维素气凝胶层、棉织物和基于铜纳米线(CuNW)的导电网络(CNN)层制成。由高导电性铜纳米线组成的CNN层不仅具有更好的导电性以实现焦耳热效应,还具有人体中红外反射特性。此外,棉织物的另一面与碳纳米管/纤维素气凝胶层压在一起,使织物具有良好的光热转换能力和隔热性能。在1.8V电压下,层压织物的温度可在80s内达到70°C;恢复到室温(28.7°C)则需要500s以上。当光强调至1000W/m²时,层压织物在光照280s后的温度约为74.0°C。我们的工作为提高个人热管理织物的性能和节能提供了一种新方法。