Qiu Kaili, Elhassan Ahmed, Tian Tianhe, Yin Xia, Yu Jianyong, Li Zhaoling, Ding Bin
Key Laboratory of Textile Science and Technology, Ministry of Education, College of Textiles, Donghua University, Shanghai 201620, China.
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China.
ACS Appl Mater Interfaces. 2020 Mar 4;12(9):11016-11025. doi: 10.1021/acsami.9b23099. Epub 2020 Feb 19.
Controlling thermal energy is one of the biggest concerns along with the progress of human civilization for thousands of years. Current thermal comfort devices are mainly based on materials that are bulky, rigid, and heavy, largely limiting their widespread practical applications. It still remains a challenge to develop highly lightweight, flexible, and efficient electrical heaters for personal thermal management and local climate control. In this work, we present a high-performance composite infrared radiation heating fabric (IRHF), which mainly consists of two layers of poly(ethylene terephthalate) (PET) fabrics and one sandwiched layer of carbon nanofibers embedded with different inorganic nanoparticles. A copper electrode sheet was connected with the carbon nanofibers to form a conductive heating circuit. The permanent spontaneous polarization of both carbon nanofibers and infrared radiation nanoparticles can facilitate an enhanced current in the heater by creating an additional electrical field, which results in a fast electrothermal response and favorable heat preservation. The constructed IRHF could achieve an increase in the temperature to 43 °C from room temperature in 1 min under a voltage of 30 V, with an electrothermal conversion efficiency up to 78.99%. With a collection of compelling features such as good thermal stability, excellent flexibility and breathability, and high electrical conductivity and energy conversion efficiency, the fabricated sandwich-structured IRHF can open up new opportunities to develop smart heating textiles and wearable heating clothes in many fields.
数千年来,随着人类文明的进步,控制热能一直是人们最为关注的问题之一。当前的热舒适设备主要基于笨重、刚性且沉重的材料,这在很大程度上限制了它们的广泛实际应用。开发用于个人热管理和局部气候控制的高度轻质、灵活且高效的电加热器仍然是一项挑战。在这项工作中,我们展示了一种高性能复合红外辐射加热织物(IRHF),它主要由两层聚对苯二甲酸乙二酯(PET)织物和一层夹在中间的嵌入不同无机纳米颗粒的碳纳米纤维组成。一个铜电极片与碳纳米纤维相连以形成导电加热电路。碳纳米纤维和红外辐射纳米颗粒的永久自发极化能够通过产生一个附加电场来促进加热器中电流增强,这导致快速的电热响应和良好的保温性能。所构建的IRHF在30V电压下,1分钟内可使温度从室温升至43°C,电热转换效率高达78.99%。所制备的三明治结构IRHF具有诸如良好的热稳定性、出色的柔韧性和透气性以及高电导率和能量转换效率等一系列令人瞩目的特性,可为在许多领域开发智能加热纺织品和可穿戴加热衣物开辟新机遇。