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未涂层结构聚对苯二甲酸乙二酯织物的人工老化机制,重点关注拉伸强度降解

Artificial Weathering Mechanisms of Uncoated Structural Polyethylene Terephthalate Fabrics with Focus on Tensile Strength Degradation.

作者信息

Asadi Hastia, Uhlemann Joerg, Stranghoener Natalie, Ulbricht Mathias

机构信息

Institute for Metal and Lightweight Structures, University of Duisburg-Essen, Universitaetsstr. 15, 45141 Essen, Germany.

Lehrstuhl für Technische Chemie II, University of Duisburg-Essen, Universitaetsstr. 7, 45117 Essen, Germany.

出版信息

Materials (Basel). 2021 Jan 29;14(3):618. doi: 10.3390/ma14030618.

Abstract

In the past five decades, reinforced coated textile membranes have been used increasingly as building materials, which are environmentally exposed. Thus, their weathering degradation over the service life must be taken into account in design, fabrication, and construction. Regarding such structural membranes, PVC (polyvinylchloride)-coated PET (polyethylene terephthalate) fabric is one of the most common commercially available types. This paper focuses on the backbone of it, i.e., the woven PET fabric. Herein, weathering of uncoated PET, as the load-bearing component of the composite PET-PVC, was studied. This study assessed the uniaxial tensile strength degradation mechanisms of uncoated PET fabric during artificial accelerated weathering tests. For this purpose, exploratory data analysis was carried out to analyze the chemical and physical changes which were traced by Fourier transform infrared spectroscopy and molecular weight measurements. Finally, with the help of degradation mechanisms determined from the aforementioned evaluations, a degradation pathway network model was constructed. With that, the relationship between applied stress, mechanistic variables, structural changes, and performance level responses (tensile strength degradation) was assessed.

摘要

在过去的五十年里,增强涂层纺织膜作为建筑材料的使用越来越多,这些材料暴露于环境中。因此,在设计、制造和施工过程中必须考虑它们在使用寿命期间的耐候性降解。对于这种结构膜,聚氯乙烯(PVC)涂层的聚对苯二甲酸乙二酯(PET)织物是最常见的商用类型之一。本文重点关注其主体,即机织PET织物。在此,研究了未涂层PET作为复合PET - PVC承重部件的耐候性。本研究评估了未涂层PET织物在人工加速老化试验期间的单轴拉伸强度降解机制。为此,进行了探索性数据分析,以分析通过傅里叶变换红外光谱和分子量测量追踪到的化学和物理变化。最后,借助上述评估确定的降解机制,构建了一个降解途径网络模型。据此,评估了施加应力、机理变量、结构变化和性能水平响应(拉伸强度降解)之间的关系。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7dc5/7866265/5e4b4db0577e/materials-14-00618-g001.jpg

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