Šaravanja Ana, Pušić Tanja, Volmajer Valh Julija, Dekanić Tihana
Faculty of Textile Technology, University of Zagreb, HR-10000 Zagreb, Croatia.
Faculty of Mechanical Engineering, University of Maribor, SI-2000 Maribor, Slovenia.
Polymers (Basel). 2024 Nov 22;16(23):3238. doi: 10.3390/polym16233238.
Aging and washing factors have a direct influence on changing the properties of textile products, e.g., causing a release of textile fragments in the washing process. In this study, polyester fabrics were exposed to artificial aging under controlled conditions. Using a modified washing process, polyester fabrics were subjected to 10 washing cycles before and after the aging process. To monitor the influence of aging and the modified washing process on the polyester fabrics, the physical, structural and morphological properties of the fabrics and the composition of the collected wastewater were analyzed. The results indicate a slight degradation and increased defragmentation of the polyester fabric due to the processes used. Aging caused the phenomenon of "annealing", photo-oxidative degradation, and the local thickening of the individual fibers. Aging and washing processes influence the change in tensile strength properties. An analysis of zeta potential and BET results confirmed that the aging process results in surface modifications that depend on the time of exposure. The physico-chemical characterization and microscopic analysis of the wastewater revealed various fragments and short, detached fibrils. The results confirmed that both aging and washing significantly affect the properties of polyester fabrics and the composition of the wastewater resulting from the washing process. The relevance of this research to environmental matters is emphasized through the parameters chosen, which reveal the influence of aging on polyester fabric characteristics and the contamination detected in wash wastewater. In conclusion, several avenues for future research have been identified, including lowering washing temperatures, choosing more appropriate detergents, and adjusting standard washing protocols.
老化和洗涤因素对纺织产品性能的改变有直接影响,例如在洗涤过程中导致纺织碎片的释放。在本研究中,聚酯织物在受控条件下进行人工老化。采用改良的洗涤工艺,聚酯织物在老化前后分别进行10次洗涤循环。为监测老化和改良洗涤工艺对聚酯织物的影响,分析了织物的物理、结构和形态性能以及收集的废水成分。结果表明,由于所采用的工艺,聚酯织物出现了轻微降解和碎片化增加的情况。老化导致了“退火”现象、光氧化降解以及单根纤维的局部增厚。老化和洗涤工艺会影响拉伸强度性能的变化。zeta电位和BET结果分析证实,老化过程会导致取决于暴露时间的表面改性。废水的物理化学表征和微观分析揭示了各种碎片和短的、分离的纤维。结果证实,老化和洗涤都会显著影响聚酯织物的性能以及洗涤过程产生的废水成分。通过所选择的参数强调了本研究与环境问题的相关性,这些参数揭示了老化对聚酯织物特性的影响以及在洗涤废水中检测到的污染物。总之,已确定了未来研究的几个方向,包括降低洗涤温度、选择更合适的洗涤剂以及调整标准洗涤方案。