Cai Deli, Wu Jinyi, Chai Ke
College of Chemical Engineering and Technology, Hainan University, Haikou 570228, China.
ACS Omega. 2021 Jan 27;6(5):3780-3790. doi: 10.1021/acsomega.0c05402. eCollection 2021 Feb 9.
The microbiologically influenced corrosion (MIC) behavior of carbon steel is investigated in the presence of and . Sterilized natural seawater inoculated with , , and the mixture of and , separately, and they are utilized as the media for corrosion characterizations, which are closer to the natural environment in seawater. Weight loss measurements, electrochemical techniques (the open-circuit potential, electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization curves), and surface analysis (scanning electron microscopy (SEM)) are performed to explore the synergistic effect of and on the corrosion behavior of carbon steel. As seen from the growth curves of bacteria, the growth and propagation of and are affected by their metabolic activities. Besides, the results obtained by SEM show that more severe pitting corrosion is observed on the coupons exposed to the sterilized natural seawater inoculated with the mixture of and . Further, the results from electrochemical measurements and weight loss measurements suggest that under the synergistic effect of and , the initial corrosion rate of carbon steel is inhibited, while the latter corrosion is enhanced.
研究了碳钢在[具体物质1]和[具体物质2]存在下的微生物影响腐蚀(MIC)行为。分别用[细菌1]、[细菌2]以及[细菌1]和[细菌2]的混合物接种经过灭菌处理的天然海水,并将其用作腐蚀特性研究的介质,这些介质更接近海水中的自然环境。通过失重测量、电化学技术(开路电位、电化学阻抗谱(EIS)和动电位极化曲线)以及表面分析(扫描电子显微镜(SEM))来探究[细菌1]和[细菌2]对碳钢腐蚀行为的协同作用。从细菌生长曲线可以看出,[细菌1]和[细菌2]的生长与繁殖受其代谢活动影响。此外,扫描电子显微镜的结果表明,在暴露于接种了[细菌1]和[细菌2]混合物的灭菌天然海水中的试片上观察到了更严重的点蚀。进一步地,电化学测量和失重测量结果表明,在[细菌1]和[细菌2]的协同作用下,碳钢的初始腐蚀速率受到抑制,而后期腐蚀加剧。