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双螺杆挤压法生产可再生纤维板。

Twin-Screw Extrusion Process to Produce Renewable Fiberboards.

机构信息

Laboratoire de Chimie Agro-industrielle (LCA), Université de Toulouse, INRAE, INPT;

Laboratoire de Chimie Agro-industrielle (LCA), Université de Toulouse, INRAE, INPT.

出版信息

J Vis Exp. 2021 Jan 27(167). doi: 10.3791/62072.

Abstract

A versatile twin-screw extrusion process to provide an efficient thermo-mechano-chemical pre-treatment on lignocellulosic biomass before using it as source of mechanical reinforcement in fully bio-based fiberboards was developed. Various lignocellulosic crop by-products have already been successfully pre-treated through this process, e.g., cereal straws (especially rice), coriander straw, shives from oleaginous flax straw, and bark of both amaranth and sunflower stems. The extrusion process results in a marked increase in the average fiber aspect ratio, leading to improved mechanical properties of fiberboards. The twin-screw extruder can also be fitted with a filtration module at the end of the barrel. The continuous extraction of various chemicals (e.g., free sugars, hemicelluloses, volatiles from essential oil fractions, etc.) from the lignocellulosic substrate, and the fiber refining can, therefore, be performed simultaneously. The extruder can also be used for its mixing ability: a natural binder (e.g., Organosolv lignins, protein-based oilcakes, starch, etc.) can be added to the refined fibers at the end of the screw profile. The obtained premix is ready to be molded through hot pressing, with the natural binder contributing to fiberboard cohesion. Such a combined process in a single extruder pass improves the production time, production cost, and may lead to reduction in plant production size. Because all the operations are performed in a single step, fiber morphology is better preserved, thanks to a reduced residence time of the material inside the extruder, resulting in enhanced material performances. Such one-step extrusion operation may be at the origin of a valuable industrial process intensification. Compared to commercial wood-based materials, these fully bio-based fiberboards do not emit any formaldehyde, and they could find various applications, e.g., intermediate containers, furniture, domestic flooring, shelving, general construction, etc.

摘要

开发了一种多功能双螺杆挤出工艺,可在将木质纤维素生物质用作全生物基纤维板的机械增强源之前,对其进行高效的热机械化学预处理。通过该工艺已成功预处理了各种木质纤维素农作物副产品,例如谷物秸秆(尤其是水稻)、芫荽秸秆、油麻纤维秸秆的皮、苋菜和向日葵茎的树皮。挤出过程导致纤维的平均纵横比显著增加,从而提高了纤维板的机械性能。双螺杆挤出机还可以在机筒末端配备过滤模块。因此,可以从木质纤维素基质中连续提取各种化学物质(例如游离糖、半纤维素、精油馏分中的挥发物等),并同时进行纤维精炼。挤出机还可以利用其混合能力:可以在螺杆末端将天然粘合剂(例如有机溶剂木质素、基于蛋白质的油饼、淀粉等)添加到精制纤维中。所得的预混合物可以通过热压成型,天然粘合剂有助于纤维板的内聚。这种在单个挤出机中进行的组合工艺可以提高生产时间、降低生产成本,并可能导致工厂生产规模缩小。由于所有操作都是在单个步骤中完成的,因此纤维形态得到了更好的保留,这要归功于物料在挤出机内的停留时间缩短,从而提高了材料的性能。这种一步挤出操作可能是有价值的工业过程强化的起源。与商业木材基材料相比,这些全生物基纤维板不会释放任何甲醛,并且可以找到各种应用,例如中间容器、家具、室内地板、货架、一般建筑等。

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