直接催化内酯的羰基/亚胺杂原子转移异构化。
Direct imidation of lactones catalytic oxo/imido heterometathesis.
机构信息
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str., 28, Moscow 119991, Russia.
出版信息
Chem Commun (Camb). 2021 Mar 11;57(21):2625-2628. doi: 10.1039/d0cc08274k.
PMID:33587064
Abstract
We report the first examples of direct imidation of lactones giving the corresponding cyclic imidates via oxo/imido heterometathesis with N-sulfinylamines catalysed by a well-defined silica-supported Ti imido complex.
摘要
我们报告了首例内酯直接亚胺化生成相应环状亚氨基碳酸酯的例子，该反应通过氧/亚氨基杂原子转移，使用 N-磺酰基胺作为亲核试剂，由负载于硅胶上的、结构明确的钛亚氨基配合物催化。
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