一种多功能的羧基镝二维金属有机框架。

A Multifunctional Dysprosium-Carboxylato 2D Metall-Organic Framework.

作者信息

González Jonay, Sevilla Pablo, Gabarró-Riera Guillem, Jover Jesús, Echeverría Jorge, Fuertes Sara, Arauzo Ana, Bartolomé Elena, Sañudo E Carolina

机构信息

Secció de Química Inorgànica, Departament de Química Inorgànica i Orgànica, Universitat de Barcelona, C/Martí i Franquès, 1-11, 08028, Barcelona, Spain.

Department of Mechanical Engineering, Escola Universitària Salesiana de Sarrià (EUSS), Passeig de Sant Joan Bosco, 74, 08017, Barcelona, Spain.

出版信息

Angew Chem Int Ed Engl. 2021 May 17;60(21):12001-12006. doi: 10.1002/anie.202100507. Epub 2021 Apr 14.

DOI:10.1002/anie.202100507

PMID:33587310

Abstract

We report the microwave assisted synthesis of a bidimensional (2D) MOF of formula [Dy(MeCOO)(PhCOO) ] (1) and its magnetically diluted analogue [La Dy (MeCOO)(PhCOO) ] (1 d). 1 is a 2D material with single-ion-magnet (SIM) behaviour and 1 d is a multifunctional, magnetic and luminescent 2D material. 1 can be exfoliated into stable nanosheets by sonication.

摘要

我们报道了式为[Dy(MeCOO)(PhCOO) ]（1）的二维（2D）金属有机框架（MOF）及其磁性稀释类似物[La Dy (MeCOO)(PhCOO) ]（1 d）的微波辅助合成。1是一种具有单离子磁体（SIM）行为的二维材料，1 d是一种多功能的磁性和发光二维材料。1可以通过超声处理剥离成稳定的纳米片。