通过I(III)介导的芳基迁移/消除实现的烯酮α-芳基化反应
Formal Enone α-Arylation via I(III)-Mediated Aryl Migration/Elimination.
作者信息
Martins Bruna S, Kaiser Daniel, Bauer Adriano, Tiefenbrunner Irmgard, Maulide Nuno
机构信息
University of Vienna, Institute of Organic Chemistry, Währinger Strasse 38, 1090 Vienna, Austria.
出版信息
Org Lett. 2021 Mar 19;23(6):2094-2098. doi: 10.1021/acs.orglett.1c00251. Epub 2021 Feb 26.
Abstract
A formal enone α-arylation is described. This metal-free transformation relies on the I(III)-mediated skeletal reorganization of silyl enol ethers and features mild conditions, good yields, and high stereoselectivities for β-substituted enones.
摘要
描述了一种形式上的烯酮α-芳基化反应。这种无金属转化依赖于I(III)介导的硅基烯醇醚的骨架重排，具有温和的条件、良好的产率以及对β-取代烯酮的高立体选择性。
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