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干湿循环作用下氯 - 硫酸根复合环境中玄武岩 - 聚丙烯混杂纤维增强混凝土的氯离子扩散性能

Chloride Diffusion Property of Hybrid Basalt-Polypropylene Fibre-Reinforced Concrete in a Chloride-Sulphate Composite Environment under Drying-Wetting Cycles.

作者信息

Luo Yang, Niu Ditao, Su Li

机构信息

Department of Civil Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China.

State Key Laboratory of Green Building in Western China, Xi'an University of Architecture and Technology, Xi'an 710055, China.

出版信息

Materials (Basel). 2021 Feb 28;14(5):1138. doi: 10.3390/ma14051138.

Abstract

The effect of fibre reinforcement on the chloride diffusion property of concrete is controversial, and the coupling effect of sulphate erosion and drying-wetting cycles in marine environments has been neglected in previous studies. In this study, the chloride diffusion property of hybrid basalt-polypropylene fibre-reinforced concrete subjected to a combined chloride-sulphate solution under drying-wetting cycles was investigated. The effects of basalt fibre (BF), polypropylene fibre (PF), and hybrid BP-PF on the chloride diffusion property were analysed. The results indicate that the presence of sulphate inhibits the diffusion of chloride at the early stage of erosion. However, at the late stage of erosion, sulphate does not only accelerate the diffusion of chloride by causing cracking of the concrete matrix but also leads to a decrease in the alkalinity of the pore solution, which further increases the risk of corrosion of the reinforcing steel. An appropriate amount of fibre can improve the chloride attack resistance of concrete at the early stage. With the increase in erosion time, the fibre effectively prevents the formation and development of sulphate erosion microcracks, thus reducing the adverse effects of sulphate on the resistance of concrete to chloride attack. The effects of sulphate and fibre on the chloride diffusion property were also elucidated in terms of changes in corrosion products, theoretical porosity, and the fibre-matrix interface transition zone.

摘要

纤维增强对混凝土氯离子扩散性能的影响存在争议,且以往研究忽略了海洋环境中硫酸盐侵蚀与干湿循环的耦合作用。本研究对干湿循环作用下处于氯化物 - 硫酸盐混合溶液中的玄武岩 - 聚丙烯混杂纤维增强混凝土的氯离子扩散性能进行了研究。分析了玄武岩纤维(BF)、聚丙烯纤维(PF)及混杂BP - PF纤维对氯离子扩散性能的影响。结果表明,硫酸盐的存在在侵蚀初期抑制了氯离子的扩散。然而,在侵蚀后期,硫酸盐不仅通过导致混凝土基体开裂加速了氯离子的扩散,还致使孔隙溶液碱度降低,进而增加了钢筋腐蚀风险。适量的纤维可在初期提高混凝土的抗氯离子侵蚀能力。随着侵蚀时间的增加,纤维有效阻止了硫酸盐侵蚀微裂纹的形成与发展,从而降低了硫酸盐对混凝土抗氯离子侵蚀性能的不利影响。还从腐蚀产物、理论孔隙率及纤维 - 基体界面过渡区的变化方面阐明了硫酸盐和纤维对氯离子扩散性能的影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c0a/7957647/90ccd565176d/materials-14-01138-g001.jpg

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