Pumchusak Jantrawan, Thajina Nonthawat, Keawsujai Watcharakorn, Chaiwan Pattarakamon
Department of Industrial Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand.
Center of Excellence in Materials Science and Technology, Chiang Mai University, Chiang Mai 50200, Thailand.
Polymers (Basel). 2021 Feb 28;13(5):754. doi: 10.3390/polym13050754.
This work aims to explore the effect of organo-modified montmorillonite nanoclay (O-MMT) on the mechanical, thermo-mechanical, and thermal properties of carbon fiber-reinforced phenolic composites (CFRP). CFRP at variable O-MMT contents (from 0 to 2.5 wt%) were prepared. The addition of 1.5 wt% O-MMT was found to give the heat resistant polymer composite optimum properties. Compared to the CFRP, the CFRP with 1.5 wt% O-MMT provided a higher tensile strength of 64 MPa (+20%), higher impact strength of 49 kJ/m (+51%), but a little lower bending strength of 162 MPa (-1%). The composite showed a 64% higher storage modulus at 30 °C of 6.4 GPa. It also could reserve its high modulus up to 145 °C. Moreover, it had a higher heat deflection temperature of 152 °C (+1%) and a higher thermal degradation temperature of 630 °C. This composite could maintain its mechanical properties at high temperature and was a good candidate for heat resistant material.
这项工作旨在探究有机改性蒙脱土纳米黏土(O-MMT)对碳纤维增强酚醛复合材料(CFRP)的力学、热机械和热性能的影响。制备了不同O-MMT含量(从0到2.5 wt%)的CFRP。结果发现,添加1.5 wt%的O-MMT可使这种耐热聚合物复合材料具有最佳性能。与CFRP相比,含有1.5 wt% O-MMT的CFRP具有更高的拉伸强度,为64 MPa(提高了20%),更高的冲击强度,为49 kJ/m(提高了51%),但弯曲强度略低,为162 MPa(降低了1%)。该复合材料在30 °C时的储能模量提高了64%,达到6.4 GPa。它还能在高达145 °C的温度下保持高模量。此外,它具有更高的热变形温度,为152 °C(提高了1%)和更高的热降解温度,为630 °C。这种复合材料能够在高温下保持其力学性能,是一种耐热材料的良好候选者。