钌(ii)催化的异邻苯二甲酰亚胺与水杨醛的脱羰基和脱羧偶联反应：得到芳基 2-氨基苯甲酸酯。
Ruthenium(ii)-catalyzed decarbonylative and decarboxylative coupling of isatoic anhydrides with salicylaldehydes: access to aryl 2-aminobenzoates.
机构信息
Applied Organic Chemistry, Chemical Sciences & Technology Division, CSIR-North East Institute of Science and Technology, Jorhat-785006, AcSIR, Ghaziabad-201002, India.
出版信息
Org Biomol Chem. 2021 Mar 28;19(12):2725-2730. doi: 10.1039/d1ob00027f. Epub 2021 Mar 8.
PMID:33683281
Abstract
A ruthenium(ii)-catalyzed coupling reaction of isatoic anhydrides and salicylaldehydes has been developed for the synthesis of 2-aminobenzoates. This reaction proceeds through metal-catalyzed decarbonylation and decarboxylation to afford good yields of aryl 2-aminobenzoates.
摘要
钌(ii)催化的异氰酸酐和水杨醛的偶联反应已经被开发用于合成 2-氨基苯甲酸酯。该反应通过金属催化脱羰和脱羧进行，得到了良好收率的芳基 2-氨基苯甲酸酯。
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