铜催化的活性亚甲基化合物与硅烷基过氧化物的选择性单烷化反应。
The copper-catalyzed selective monoalkylation of active methylene compounds with alkylsilyl peroxides.
机构信息
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China.
出版信息
Org Biomol Chem. 2021 Mar 28;19(12):2658-2662. doi: 10.1039/d1ob00075f. Epub 2021 Mar 9.
PMID:33687416
Abstract
A novel method for a mild copper-catalyzed selective monoalkylation of active methylene compounds with various alkylsilyl peroxides has been developed. The reaction has a broad substrate scope and our mechanistic studies suggest the participation of radical species in this alkylation reaction.
摘要
一种新型温和的铜催化方法，可用于各种烷基硅基过氧化物与活泼亚甲基化合物的选择性单烷基化反应。该反应具有广泛的底物范围，我们的机理研究表明自由基物种参与了这种烷基化反应。
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