用于蓝色荧光有机发光二极管的7,7-二甲基-9-(10-苯基蒽-9-基)-7H-苯并[b]芴并[3,4-d]噻吩衍生物

7,7-Dimethyl-9-(10-phenylanthracen-9-yl)-7H-Benzo[b] Fluoreno[3,4-d]Thiophene Derivatives for Blue Fluorescent Organic Light-Emitting Diodes.

作者信息

Lee Jin Ho, Han Gi Woong, Kim Ki Ju, Lee Hakjun, Kim Young Kwan, Yoon Seung Soo

机构信息

Department of Chemistry Sungkyunkwan University, Suwon, 16419, Korea.

Department of Information Display, Hongik University, Seoul, 04066, Korea.

出版信息

J Nanosci Nanotechnol. 2021 Sep 1;21(9):4665-4669. doi: 10.1166/jnn.2021.19294.

DOI:10.1166/jnn.2021.19294

PMID:33691848

Abstract

In this study, we designed and synthesized two blue fluorescence materials using 7,7-dimethyl-9-(10-phenylanthracen-9-yl)-7H-benzo[b]fluoreno[3,4-d]thiophene substituted anthracene derivatives. To characterize their electroluminescent properties, we fabricated the OLED devices using these two emitting materials. Particularly, a device using 7,7-dimethyl-9-(10-phenylanthracen-9-yl)-7Hbenzo[ b]fluoreno[3,4-d]thiophene showed maximum values of luminous efficiency, power efficiency, and external quantum efficiency of 2.42 cd/A, 1.48 lm/W, 3.08% at 20 mA/cm2, respectively with CIE () coordinates of (0.15, 0.09) at 8.0 V.

摘要

在本研究中，我们使用7,7-二甲基-9-(10-苯基蒽-9-基)-7H-苯并[b]芴并[3,4-d]噻吩取代的蒽衍生物设计并合成了两种蓝色荧光材料。为了表征它们的电致发光性能，我们使用这两种发光材料制备了有机发光二极管（OLED）器件。特别地，使用7,7-二甲基-9-(10-苯基蒽-9-基)-7H-苯并[b]芴并[3,4-d]噻吩的器件在20 mA/cm² 时的发光效率、功率效率和外量子效率的最大值分别为2.42 cd/A、1.48 lm/W、3.08%，在8.0 V时的CIE（）坐标为(0.15, 0.09)。